静电纺丝制备 PVDF 压电微纳米纤维膜及其诱变机制研究.pdf

Polyvinylidene fluoride, PVDF PVDF αβγδ ε β PVDF β PVDF PVDF PVDF β FTIR-XRD PVDF β γ β PVDF —Lambert-Beer Law Gregorio β Fβ 16 wt%VNMP/Vacetone =2/8 ~ 6/4β Fβ95% 98.6%Fβ Fβ Fβ PVDF β β F(β) ~ 94.9% β β I PVDF PVDF PVDF β PVDF β PVDF γPVDF II Abstract Abstract Polyvinylidene fluoride (PVDF), the only widely used as flexible piezoelectric material, presents the highest pieozoelectricity among all piezoelectric polymers. At least, five crystalline phases, i.e. α, β, γ, δ, and εphases, are known to exist in PVDF. Among them, the β phase shows the best piezoelectric activity, which attracts people’s interest. A process of stretching and the poling followed is thought to be the regular way to obtain the piezoelectric PVDF membranes. However, the traditional cold-drawing and high-temperature strong electrical poling approach is difficult to achieve high-level β phase, and also complicated, time-consuming, resource-wasting, etc., which limits its application. Recent electrospinning technology has received great attention in fabricating piezoelectric PVDF membrances, because it combines stretching and electrical poling i