石油炼厂废水处理的不同聚合物混凝剂评估Evaluation of different polymer.docxVIP

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石油炼厂废水处理的不同聚合物混凝剂评估Evaluation of different polymer.docx

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Evaluation of different polymeric coagulants for the treatment of oilrefinery wastewater 石油炼厂废水处理的不同聚合物混凝剂评估 E.K.Tetteh Abstract摘要： Wastewater from oil refinery industries has major pollution potentials with mutagenic and toxic compounds. Due to water scarcity in South Africa, oil refinery industries are compelled to find appropriate technology to treat their wastewater for reuse. With regards to this, most of the chemo-physical treatment processes are inadequate and are faced with major environmental and economic challenges. Therefore, this study aimed to find replaceable and cost-effective coagulants to the conventional coagulant for the treatment of a local South Africa oil refinery wastewater using dissolved air flotation (DAF) Jar tests. Three polymeric coagulants for the removal of turbidity, total suspended solids, chemical oxygen demand, and soap oil and grease (SOG) were investigated. At defined experimental conditions of recycle ratio (10%), air saturator pressure (350 kPa) and pH at 5, each coagulant was evaluated from a dosage of 10 mg/L to 50 mg/L. Above 80% of the aforementioned oily pollutants were removed at the coagulant dosage of 50 mg/L. Among the coagulants evaluated, PASS was found as the most suitable alternative coagulant to alum, to enhance and aggregate the air bubble-oil droplet interface for easy separation by the DAF. From the results, PASS is foreseen as promising and economical for pre-treatment of industrial wastewater, which is due to its lower cost and easy degradability. 炼油行业致突变和有毒化合物的污染潜力巨大。由于南非缺水，炼油行业不得不寻求合适的再利用废水处理技术。就此而言，多数化学-物理处理工艺不充分，面临重大环境和经济挑战。因此，本研究目的通过溶气浮选(DAF)烧杯试验，发现可替代传统混凝剂且成本效率高混凝剂，用于处理南非当地炼油厂废水。研究了三种去除浊度、总悬浮固体、化学需氧量和皂油和油脂(SOG)的聚合物混凝剂。在循环率(10%)、空气饱和器压力(350 kPa)和pH为5的规定实验条件下，评估了投加量为10 mg/L到50 mg/L的每种混凝剂。混凝剂投加量为50 mg/L,去除上述油污染物80%以上。在评估的混凝剂中，发现 PASS是最适合替代硫酸铝的混凝剂，可增强和聚集气泡-油滴界面，易于由DAF别离。携式色度测量TSSo SOG测试采用南非标准局(SABS)方法1051的萃取(二氯甲烷) 和干燥水分(硫酸钠)技术。 Results and discussion结果和讨论DAF performance 性能 DAF being a separation pro