论文：相变储能材料专用蜡的开发.pdfVIP

天津大学 硕士学位论文 相变储能材料专用蜡的开发 摘要 应对国内外对开发新能源的趋势和对储能材料的市场需求，本文研究开发 了系列相变储能材料及其生产工艺。 采用南阳石蜡精细化工厂石油蜡为主要原料，通过对脱蜡方式、条件、储 程等进行选择，确定了溶剂脱蜡、减压分储的生产工艺，并对关键指标相变焰的 影响因素进行了综合考察，经过大量实验研究，成功地开发出了应用于建筑行业 的相变储能专用蜡。产品物性指标测试结果表明，所开发的相变储能专用蜡的熔 点、相变结等指标达到现行国内企业标准，并且正构燃含量高，碳数分布集中， 产品熔值高于日本同类产品指标要求，可以满足国内建筑行业储热材料的需要。 本文研究开发了生产相变储能专用蜡的工艺技术，并进行了小试和中试放 大。结果表明，所开发的工艺产品质量稳定，生产过程不产生“三废”，符合环 保要求。采用中试工艺生产的相变储能专用蜡在清华大学进行了工程化应用试 验，结果表明，该蜡工艺性能稳定，相变温差小、相变热大，完全满足相变储能 材料的工艺要求；相变蜡的各项性能与国外同类产品相当，并且是国内首次利用 石油蜡生产相变储能材料，填补了该项目国内空白。 相变储能专用蜡的开发成功，对提高我国建筑行业储热材料的研究水平、 提高石油蜡的产品附加值，具有重要意义。 关键词：储能材料，蜡，相变始，分储 ABSTRACT Considering the international developing trend of new energy resource and the domestic market demand of restored energy materials, this paper researched series phase change stored energy material specific wax, developed small and middle scale technology to produce them. With Nanyang petroleum wax as main raw material, we select the dewaxing methods, dewaxing conditions and distillation range, determine the produce technology of solvent dewaxing and decompression distillation, and investigatethe influence factor of phase change enthalpy. Through lots of experiments, we successfully developed phase change stored energy material specific wax. The results of series experiment showed that all physical indexes of new products such as melting point, phase change enthalpy can meet present domestic enterprise standards. Also the products have high content of normal paraffin, assembling carbon distribution and enthalgy value is higher than Japanese ones. In this paper small and middle scale technology to produce phase change stored energy material specific wax were developed The results of experiments showed that the n