固相萃取片法分析土壤中的99Tc.pdfVIP

固相萃取片法分析土壤中的 99 Tc 杨素亮;丁有钱;梁小虎;宋志君;孙宏清;张生栋 【摘要】系统研究了阴离子固相萃取片分离水溶液中 TcO-4 的性能,包括流速、酸 度、体积、土壤基质对吸附的影响。在此基础上,针对土壤中 99 Tc 含量的分析,建 立了以固相萃取片法为主要分离手段、液闪为放射性测量方法的分析流程,并利用 模拟 99 Tc 污染土壤样品对分析流程进行了检验。研究结果表明,土壤中含有的本 底放射性核素及常见沾污核素 137 Cs、90 Sr-90 Y 和天然铀对分析流程均无明显 干扰,全流程 99 Tc 的化学收率在 95%以上。样品质量为 10 g、液闪测量能量范围 本底计数率为 10 min-1、测量时间为 10 h 时,方法的最小可探测浓度约为 0.07 min-1·g-1,即 1.1 Bq/kg。%The performance of anion solid phase extraction disk for the separation of TcO-4 ion in aqueous solution was studied systematically.The effects of flow rate,acid-ity,sample volume and soil matrix on adsorption were evaluated with different flow rate load conditions.And on this basis,an analysis procedure using solid phase extraction disk for the routine determination of 99 Tc in soil was presented.The procedure was vali-dated by some simulated contaminated soil samples.The results show that 137 Cs,90 Sr-90 Y,natural uranium and background radionuclides in soil do not interfere with the anal-ysis procedure.The chemical yield of technetium is more than 9 5% for the whole proce-dure.The minimum detectable concentration is 1.1 Bq/kg with sample quantity of 10 g, background counting rate of 10 min-1 and detection time of 10 h. 【期刊名称】《原子能科学技术》 【年(卷),期】2015(000)011 【总页数】6 页(P1926-1931) 【关键词】土壤;99 Tc;固相萃取片 【作者】杨素亮;丁有钱;梁小虎;宋志君;孙宏清;张生栋 【作者单位】中国原子能科学研究院 放射化学研究所，北京 102413;中国原子能 科学研究院 放射化学研究所，北京 102413;中国原子能科学研究院 放射化学研究 所，北京 102413;中国原子能科学研究院 放射化学研究所，北京 102413;中国原 子能科学研究院 放射化学研究所，北京 102413;中国原子能科学研究院 放射化学 研究所，北京 102413 【正文语种】中 文 【中图分类】O658.1 ion in aqueous solution was studied systematically. The effects of flow rate, acidity, sample volume and soil matrix on adsorption were evaluated with different flow rate load conditions. And on this basis, an analysis procedure using solid phase extraction disk for the routine determination of 99Tc in soil was presented. The procedure was validated by some simulated contaminated soil samples. The results sh