炭化条件对竹原纤维炭孔隙结构的影响分析.pdfVIP

炭化条件对竹原纤维炭孔隙结构的影响分析 摘 要: 为研究炭化竹原纤维的特性，进一步提升竹原纤维的使用性能，拓宽竹原纤维的应用领域，采用 可控电炉制备了不同炭化温度和不同保温时间条件下的炭化竹原纤维，利用全自动比表面积及孔隙度分析 仪测试了炭化竹原纤维的比表面积、比孔容及平均孔径，探讨了炭化条件对其性能的影响。结果表明：随 炭化温度的升高和保温时间的延长，炭化竹原纤维的比表面积、比孔容和孔径分布先增大后减小，在较优 的工艺条件下，炭化竹原纤维的比表面积和比孔容最大值分别可达819.35 2 和 3 ，平均孔径最 m /g 0.7358 cm /g 小可达2.0836 nm 。 关键词: 竹原纤维；比表面积；比孔容；平均孔径 Analysis of the Effect of Carbonization Conditions on Bamboo Fiber Charcoal Pore Structure Zhang Min, Yan Guoqi, Zhang Wenbiao* (School of Engineering, Zhejiang Agriculture and Forestry University Li`nan 311300, China.) Abstract: In order to study the characteristics of carbonized natural bamboo fibers and improve properties and broaden application fi elds of natural bamboo fi bers, electric furnace was used to produce carbonized natural bamboo fi bers at different carbonization temperatures and soaking times, and accelerated surface area and porosimetry system was used to measure their pore structure. Then the effect of carbonization temperature and soaking time on specifi c area, specifi c pore volume and mean diameter of carbonized fi bers was discussed. The results showed that specifi c area, specifi c pore volume and mean diameter increased fi rstly and then decreased with the rise of carbonization temperature and soaking time. Under superior processing conditions, the highest values of specifi c area and specifi c 2 3 pore volume were 819.35 m /g and 0.7 358 cm /g respectively and the lowest value of mean diameter was 2.0 836 nm. Key Words: natural bamboo fi bers, specifi c area, specifi c pore volume, mean diameter 竹原纤维是采用物理脱胶法或微生物脱 入氧气的条件下炭化得到的固体产物，具有 胶法从竹材中直接提取的纤维，制取方法有 孔结构发达、比表面积大、释放负离子和远 化学机械法、蒸煮锤击法或碾压开