高庙子膨润土在模拟水泥浸出液中的黏土矿物相变.pdfVIP

高庙子膨润土在模拟水泥浸出液中的黏土矿物相变

摘要：高放废物处置库衬砌混凝土，在地下水溶蚀作用下释放出“水泥浸出液”，其化学成分经历4个阶段的演变过程。配

制新鲜水泥浸出液模拟第I阶段水泥浸出液，与高庙子膨润土粉末混合成悬液体系，开展批式固–液静态反应，评估中国处置

库膨润土缓冲材料的长期化学稳定性。静态反应256d期间，分阶段采收的悬液分离成固、液两相。液相检测pH值、电导

率和阳离子浓度。固相开展X射线衍射、Fourier红外光谱和扫描电子显微镜–能谱仪分析测试。固、液两相分析结果表明：

高庙子膨润土在新鲜水泥浸出液作用下，同时发生蒙脱石矿物的溶解及伊利石/蒙脱石混层次生矿物的形成，从而降低高庙子

膨润土的缓冲性能。

关键词：高放废物处置；缓冲屏障；模拟水泥浸出液；膨润土；蒙脱石

ClayPhaseChangeofGaomiaoziBentoniteinSimulatedCementSolutions

Abstract:Becauseofgroundwaterdissolution,theliningconcreteofHLWgeologicalrepositoryreleasea“cementsolution”,andits

chemicalcompositionundergoesafour-stageevolutionprocess.AyoungcementsolutionstandingforI-stagecementsolutionwas

mixedwithGaomiaozi(GMZ)bentonitepowder,assuspensionstopromptstaticsolid-liquidreactioninabatchstyleforevaluation

oflong-termchemicalstabilityofthebentonitebuffermaterialasusedinChina.During256dtest,suspensionswereharvestedin

differenttimeintervalsandseparatedintosolidandliquidphases.TheliquidphasewereanalyzedforpH,electricalconductivityand

cationconcentration.ThesolidphasewascharacterizedbymeansofX-raydiffraction,Fouriertransforminfraredspectraand

scanningelectronmicroscope–energyspectrum.Theanalysisresultsofsolidandliquidindicatedboththedissolutionof

montmorillonitemineralandtheformationofmixedlayerillite–smectiteoccurinGMZbentoniteatthesametimeundertheactionof

youngcementsolution.ThistendstoreducethebufferperformanceoftheGMZbentonite.

Keywords:highlevelwastedisposal;bufferbarrier;simulatedcementsolution;bentonite;montmorillonite

核电工业发展过程中不可避免会产生“放射