有机硅氧烷封端聚氨酯密封胶化学.ppt

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2025-02-19 发布于四川
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有机硅氧烷封端聚氨酯密封胶化学.ppt

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有机硅氧烷封端聚氨酯密封胶化学

OrganofunctionalSilanes-GeneralStructureY(CH2)nSi(OR)3n = 0,3R = CH3,C2H5,(CH2)2OCH3Y = OrganofunctionalgroupY(CH2)nSiORORORBifunctionalmoleculehydrolysablenonhydrolysable

HydrolysisandCondensation:AMoreRealisticScenario

SiOSiSiSiSiSiYYYOOOOOOYYYO2-/3-Dimensionalpolysiloxanes(Network/gelformation)Catalyst(H+)SilaneYSiORORORSilanetriolYSiOHOHOHSilanediolORYSiOHOHSilanolORYSiOROHDisiloxaneORORYYSiSiOOROR+H2O-ROH+H2O-ROHCondensationCondensation(-H2O)

HydrolysisofTheSilane’sAlkoxyGroupsImportantfactorsforhydrolysis?pH-value ?concentration?typeofcatalyst?temperature?solvent ?organofunctionalgroup?alkoxyfunctionalgroup:-OMe-OEtY-(CH2)3-Si(OR)3H+-catalyzed-OH-catalyzedrapidgelation(crosslinking)slowgelation(linear)

SilanereactivitytoinorganicmaterialsGoodSlightNoneExcellentSilica,Quartz(白碳黑,石英)GlassAluminum,CopperAlumino-Silicates(Clays)(粘土)Mica(云母)TalcInorganicOxides(e.g.TiO2,Fe2O3,ATH,MGHetc.)Steel,IronAsbestosNickel,Zinc,LeadChalk(CaCO3)(碳酸钙)Gypsum(CaSO4)(硫酸钙)Barytes(BaSO4)Graphite,CarbonBlack(碳黑)

ReactivityofVariousSubstrates

TowardsOrganofunctionalSilanesGlassfiberGlassandmineralwoolQuartzflour,silica,sandCristobaliteWollastoniteMicaCorundumAluminiumtrihydroxideMagnesiumdihydroxideKaolinTalcIronoxidesTitaniumoxidesOtherinorganicpigmentsCarbonblackCalciumcarbonate(chalk)BariumsulphateCalciumsulphate(gypsum)InorganicfillersCopperAluminumSilverSteelZincMetalsPolyamidePolycarbonatePolyesterPolyacrylatePolymethylmethacrylatePolyolefinsPolymersgoodbadSilkCottonWoodSisalCoconutFlax...Naturalfibers

AdhesivesCoatingsElastomersElectronicsFiberglassFoundryMineralFillerTreatmentSealantsPolyolefinCrosslinkingEtc.PrincipalSilaneMarkets

SilanesMarketSegmentsAdhesivesSealantsArchitecturalCoatingsWoodCoatings-ClearVarnishElastomers(TireandShoeSoleApplications)Electronics(EMC)FiberglassCopperFoilLaminationFoundryMineralfil