热处理工艺对17-4PH不锈钢氧化皮结构及其腐蚀行为的影响.docxVIP

《?????》2019?4??48??8?

??????17-4PH?????????????????

???1,???1,???2,???1

(1.???????????????,??300300;2.??????????,??300300)

??：????????、?????17-4PH???????????????。??????（SEM）、X?????（XRD）????????????????????17-4PH??????????????3.5wt%NaCl????????。????：?????????17-4PH????????????????????????????????，???????????????????????。??????Fe3O4?Fe2O3??。?????????????????，Fe2O3???????，???????????????，??????????????。550℃??12h???????17-4PH??????????????。

???：17-4PH???；?????；???；???DOI:10.14158/j.cnki.1001-3814.2019.08.037

?????：TG172.5 ?????：A ????：1001-3814(2019)08-0149-05

EffectsofHeatTreatmentProcessonStructureandCorrosionBehaviorof17-4PHStainlessSteelOxideScale

CHENYajun1,ZHANGXuntao1,LIUSicheng2,SONGXiaoxiao1

(1.Sino-EuropeanInstituteofAviationEngineering,CivilAviationUniversityofChina,Tianjin300300,China;2.AerospacePrecisionCo.,Ltd.,Tianjin300300,China)

Abstract：Oxidescaleswithdifferentstructureswerepreparedonthesurfaceof17-4PHstainlesssteelbycontrollingtheoxidationtemperatureandholdingtime.Thescanningelectronmicroscopy(SEM),X-raydiffraction(XRD)andelectrochemicaltestmethodswereusedtoinvestigatethestructureofoxidizedsurfaceandcorrosionbehaviorin3.5wt%NaClsolution.Theresultsshowthatwiththeincreaseoftheoxidationtemperature,thestructureofoxidescaleschangesfromcotton-likewithgullytoflake-likesmallparticleswithburrs,andtheprolongingofholdingtimeishelpfultothereductionofdefectsbetweensmallparticles.Theoxidescaleof17-4PHstainlesssteelmainlyconsistsofFe3O4andFe2O3phases.TherelativecontentofFe2O3increaseswiththeincreaseoftheoxidationtemperatureandholdingtime.Theincreaseoftheoxidationtemperatureandtheprolongingoftheholdingtimecontributetotheincreaseofthecompactnessandcontinuityoftheoxidescale,therebyimprovingthecorrosio