复旦 高分子化学课件for copy-ATRP.pptVIP

FUDANAtomTransferRadicalPolymerization

AtomtransferradicalpolymerizationFUDANThefirstpaper:

MechanismofATRPFUDAN

MolecularweightanddistributionFUDAN

KineticsFUDAN

Monomers:widersuitabilityFUDANStyrenics:Methacrylates:

Monomers:widersuitabilityFUDANAcrylates:

InitiatorsFUDAN1.Alkylhalides:

InitiatorsFUDAN2.?-haloesters,ketonsandnitriles

InitiatorsFUDAN3.Sulfonylhalides:muchfasterinitiation,easytogenerate,hardtoterminate,highefficiency.

TheoreticalresultsFUDAN

LigandsFUDAN

MetalcomplexesFUDAN

MacromolecularengineeringbyATRPFUDANTerminalfunctionalization:

Dendritic-lineardiblockcopolymerFUDAN

Polymerbrushes:denselygraftedcopolymersFUDANATRP

Star-likepolymersFUDAN

HyperbranchedpolymersFUDANSelf-condensingvinylpolymerization:

CompositionalcontrolFUDAN

SummaryFUDAN

SyntheticstrategyofstarpolymersusingATRPFUDANStarpolymerswithexactnumberofarms;Starpolymerswithcrosslinkedcore;

Linearmacroinitiatorasthechainprecursor:FUDAN“Armfirst”approachLinearmacromonomerasthechainprecursor:SyntheticstrategyofstarpolymersusingATRP“Corefirst”approach

Linearmacroinitiatorvs.macromonomer:FUDAN“Armfirst”approachStericsaturationstate

Chainend-linking:FUDANMacroinitiatorapproachCorecross-linking:Drawback:Star-Starcoupling

Anexampleof“Armfirst”synthesis

Corefunctionalizedstarpolymer:FUDAN“Armfirst”approach

FUDANThecrosslinkers

By“in-out”method:FUDANMiktoarmsBy“co-linking”method:

FUDAN“Core-first”approachStarfromin-situgeneratedcore

FUDANOne-potsynthesisofhairynanoparticlesinemulsion

HairynanoparticlesFUDAN

ComparisonofdifferentsystemsInatomtransferradicalcopolymerization,oranykindoflivingcopolymerization,ofvinylanddivinylmonomer,theadditionofthelatterdeterminesthestructureofthefinalproduct.FUDAN

MorehomogenousgelsbyCRP:FUDANCrosslinkingreaction:synthesisofnetworks

SomefeaturedsystemsdevelopedbyMatyjaszewskiBasedonPRE

FUDAN