第四章 核磁共振.pptVIP

NuclearMagneticResonanceSpectroscopyPrinciplesAbsorptionofelectromagneticradiationintheradio-frequencyregionofthespectrumresultinginchangesintheorientationofspinningnucleiinamagneticfield.NMR:具有磁性的原子核在强磁场作用下,受到

某一射频照射时,产生磁诱导效应的过程

核磁共振分类:1,1H1NMR谱，proton-NMR2,13C6NMR谱，carbon-NMR3,19F9NMR谱4,31P15NMR谱Forhydrogen(I=?),therearetwospinstates(2(?)+1=2)foritsnucleus:clockwise(+?)orcounterclockwise(-?)spin.Intheabsenceofanexternalmagneticfield,thesemagneticmomentsarerandomlyorientedinalldirections.Ifanexterna