国外标准分享ASTM F2013-00.docxVIP

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Designation:F2013–00

StandardTestMethodfor

DeterminationofResidualAcetaldehydeinPolyethyleneTerephthalateBottlePolymerUsinganAutomatedStaticHead-SpaceSamplingDeviceandaCapillaryGCwithaFlameIonizationDetector1

ThisstandardisissuedunderthefixeddesignationF2013;thenumberimmediatelyfollowingthedesignationindicatestheyearoforiginaladoptionor,inthecaseofrevision,theyearoflastrevision.Anumberinparenthesesindicatestheyearoflastreapproval.Asuperscriptepsilon(e)indicatesaneditorialchangesincethelastrevisionorreapproval.

Scope

Thistestmethodcoversagaschromatographicproce-dureforthedeterminationoftheppmresidualacetaldehyde(AA)presentinpoly(ethyleneterephthalate)(PET)homo-polymersandco-polymerswhichareusedinthemanufactureofbeveragebottles.Thisincludessampletypesofbothamorphousandsolid-statedpelletandpreformsamples.

Thisstandarddoesnotpurporttoaddressallofthesafetyconcerns,ifany,associatedwithitsuse.Itistheresponsibilityoftheuserofthisstandardtoestablishappro-priatesafetyandhealthpracticesanddeterminetheapplica-bilityofregulatorylimitationspriortouse.

ReferencedDocuments

ASTMStandards:

D4509TestMethodforDeterminingthe24-HourGas(Air)SpaceAcetaldehydeContentofFreshlyBlownPETBottles2

Terminology

Thetermsemployedinthistestmethodarecommonlyusedinnormallaboratorypracticeandrequirenospecialcomment.

SummaryofTestMethod

Aspecifiedsize(800to1000μm)ofgranulatedsampleisweighedintoa20-mLhead-spacevial,sealed,andthenheatedat150°Cfor60min.Afterheating,thegasabovethesealedsampleofPETpolymerisinjectedontoacapillaryGCcolumn.Theacetaldehydeisseparated,andtheppmofacetaldehydeiscalculated.

SignificanceandUse

Thistestmethodisofparticularuseasaqualitycontroltoolforamoldingorsynthesisoperation.Acetaldehydei