稀薄溶液的依数性质课件.pptVIP

例：10g/L蔗糖(C12H22O11)水溶液的密度1(g/ml)(蔗糖Mr=342)，計算其品質摩爾濃度bB。解：10(g/L)=10g溶質1000ml溶液nB=10/Mr=10/342mA=1000×1－10(g)(溶劑品質)bB=nB/mA=1000×(10/342)/(1000×1-10)=0.030(mol.kg-1)溶液的沸點升高和凝固點降低例：10g/L蔗糖(C12H22O11)水溶液的密度1(g/ml)(蔗糖Mr=342)，計算該溶液的沸點和凝固點。解：bB=0.030(mol.kg-1)根據：⊿Tb=Kb·bBKb=0.512⊿Tb==0.015(K)Tb=⊿Tb+Tb0=0.015+373=373.015(K)或=0.015+100=100.015(℃)×0.0300.512前面已計算溶液的沸點升高和凝固點降低解：bB=0.030(mol.kg-1)根據：⊿Tf=Kf·bBKf=1.86⊿Tf==0.056(K)Tf=Tf0－⊿Tf=0.0－0.056=-0.056(℃)或=273－0.056=272.44(K)1.86×0.030溶液的沸點升高和凝固點降低例：10g/L蔗糖(C12H22O11)水溶液的密度1(g/