储氢材料02-Hydrogen Storage materials.PPTVIP

Tel: 0571- 8795 1152 Email: lxchen@zju.edu.cn Laboratory of Hydrogen Storage Materials Institute of Metallic Materials Zhejiang University Hydrogen Storage Materials Dr. Li-xin Chen Fundamental properties of HSAs 1) large hydrogen storage capacity long pressure plateau of P-C-T curve easily activation flat and suitable pressure plateau small hysteresis of P-C-T curve －small ln(Pab/Pdes) Fundamental properties of HSAs 5) suitable enthalpy |?H| suitable Peq H2 (a) ordinary storage: -10 kcal/ mol H2； (b) separation: lower Peq H2 ( 1atm ), lower |?H| (少化辅助热)； (c) compression: high |?H| ; (compression ratio Ph/Pl) (d) thermo- storage: high |?H| . (同量的氢可蓄更多的热) Fundamental properties of HSAs 6) good kinetics－high absorption/desorption rate 7) good stable in environment gaseous: O2, H2O, CO2, SO2, CO, Cl2 electrolyte: KOH, NaOH 8) slow cycling degradation (循环衰退) 9) low cost Rare Earth Based Hydrogen Storage Alloys Lecture II I . Basics of Rare Earth Positions in periodic table: Ⅲ B group 6th period and 7th period China has the most abundant rare earth resource (~80%) in the world. 1) 6th period — La series 15 elements (light rare earth) I . Basics of Rare Earth 2) 7th period — Ac series 15 elements (heavy rare earth, radioactive) I . Basics of Rare Earth 2.1 LaNi5 1968 Found the hydriding/dehydriding properties of LaNi5 by Philips Lab. (published in 1970) SmCo5 → LaNi5 can absorb/desorb H2 at room temp. Ⅱ. Rare Earth Based Binary HSAs 1) Suitable thermodynamic properties Features: a) pressure plateau: Pa=2.3 atm, Pd=1.9 atm at room temp. T= 40℃ T= 80℃ T= 20℃ P-C-T curves of LaNi5-H system high capacity: H/LaNi5 = 6~6.7 at 20℃ and 25 atm. easily activation . 2.1 LaNi5 2) Good kinetics Rate of H absorption is very fast, limited by heat diffusibility. ?P=Po–Peq.H2 ?H → T↑ → Peq.H2↑ → ?P↓ 3) Good anti-oxidation property for gas-solid reaction O2, CO2, H2O (g) － light effec