Eu3+掺杂一维硅酸钙纳米荧光粉的水热合成及其发光性能.docVIP

  Eu3+掺杂一维硅酸钙纳米荧光粉的水热合 成及其发光性能# 林良武1，孙心瑗2，江垚1，贺跃辉1* 5 10 15 20 25 30 35 40 （1. 中南大学粉末冶金国家重点实验室，长沙 410083； 2. 井冈山大学数理学院， 江西 吉安 343009） 摘要：本文采用溶胶-水热法成功合成出新颖的近紫外和蓝光激发型 Eu3+掺杂一维硅酸钙纳 米荧光粉。采用 SEM、TEM、HRTEM、XRD、FTIR、PL 和 PLE 光谱表征了 Eu3+掺杂一维 硅酸钙纳米荧光粉的形貌、微结构、化学成分及其光学性能。研究结果表明制备的 Eu3+掺杂 硅酸钙纳米线为单晶纳米线，直径分布在 5-60nm 之间，平均直径约为 25nm，长度达几十 至几百微米不等，Eu3+离子均匀掺入硅酸钙纳米线基质中。PL 和 PLE 研究的结果表明 Eu3+ 掺杂硅酸钙纳米线能被 395nm 的近紫外光和 465nm 的蓝光有效激发，可发出强的蓝、橙、 红三色光，这表明制备的 Eu3+掺杂硅酸钙纳米线在白光 LED 用荧光粉领域具有巨大的潜在 应用价值。 关键词：硅酸钙纳米线；纳米荧光粉；白光 LED；发光性能 中图分类号：TB39 Hydrothermal synthesis and Optical property of Eu3+-doped one-dimensional Calcium Silicate nano-phosphors LIN Liangwu1, SUN Xinyuan2, JIANG Yao1, HE Yuehui1 (1. State Key laboratory for Powder Metallurgy, Central south University, ChangSha 410083; 2. School of Mathematics and Physics, Jingangshan University, JiangXi JiAn 343009) Abstract: In this study, a novel near-UV and blue excited Eu3+-doped one dimensional calcium silicate nano-phosphors have been synthesized successfully by a simple and facile sol- hydrothermal method. Through Field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscope (HRTEM) equipped with energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FTIR), photoluminescence (PL) and photoluminescence excitation (PLE) spectra, the morphologies, microstructure, chemical constitution and optical property of the resulting samples were characterized. The results suggested that the obtained nanowires are single crystal Eu3+-doped calcium silicate nanowires with the diameter between 5-60nm and average diameter around 25 nm and the length range from tens to hundreds micrometers. The results of PL and PLE indicated that the Eu3+-doped single crystal calcium silicate nanowires showed an intensive blue， orange and red light emission under excitation at 394 and 465nm, which suggest that the obtained novel 1D nano-phosphors have the potential applicat