ZnO和ZnS纳米复合材料的水热法制备.doc

  ZnO 和 ZnS 纳米复合材料的水热法制备 张存磊1，席珍强2** （1. 浙江理工大学材料与纺织学院，杭州 310018； 5 10 15 20 25 30 35 40 2. 浙江理工大学材料工程中心，杭州 310018） 摘要：以 Zn( NO3)2 · 6H2O 和 NaOH 为原料，利用水热法制备出花状的氧化锌。把氧化锌 分散在硫代乙酰胺水溶液中，通过二次水热反应，制备出一种新颖的片状结构的 ZnO/ZnS 纳米复合材料。采用 X 射线衍射仪( XRD)、扫描电子显微镜(SEM)、能谱仪( EDS) 等测试 手段对 ZnO/ ZnS 纳米片晶体结构和表面形貌进行了表征。测试结果得知，纳米片是由 ZnO 与 ZnS 组成的复合材料，呈现不规则形状，厚度约为 20-30nm。通过控制硫代乙酰胺的浓度 可以调节 ZnS 的含量。紫外可见光漫反射吸收光谱表明，纳米片在可见光区域表现出非常 低的吸收率，377nm 附近的吸收边出现蓝移现象，在 432nm 处增加了一个吸收峰。随着 S 元素的增多，ZnO 的禁带宽度从 3.21eV 增加大 3.26eV。 关键词：ZnO；ZnS；水热法；纳米复合材料 中图分类号：O781 Hydrothermal synthesis of ZnO and ZnS nanocomposite materials Zhang Cunlei1, Xi Zhenqiang2 (1. Zhejiang Sci-Tech University,Faculty of Materials and Textiles, HangZhou 310018; 2. Zhejiang Sci-Tech University ,Materials Engineering Center, HangZhou 310018) Abstract: The flower-like ZnO was prepared by hydrothermal method with Zn (NO3)2· 6H2O and NaOH as reactive materials. The novel sheet structure of zinc oxide and zinc sulfide nano composite material was formed through zinc oxide dispersed in Thioacetamide solution. The crystal structure and morphology of the as -synthesized samples were investigated by means o f X-ray diffraction(XRD),scanning electronmicroscope(SEM) and energy dispersive X-ray spectroscopy(EDS) . The results show that the as -synthesized indicated that sheet crystal structure is composed of both ZnO and ZnS with irregular shape and thickness of about 20-30nm, through the control of thioacetamide concentrations could regulate the content of ZnS. UV-vis diffuse reflectance spectroscopy show that the sheet structure have a very low absorption rate in visible region and 371nm near the absorption edge have blue shift phenomenon with an new absorption peak of 432nm arise。With the increase of S elements，the forbidden band width of ZnO is increased from 3.21ev to 3.26ev. Keywords: ZnO; ZnS; hydrothermal method; nanocomposite material 0 引言 氧化锌和硫化锌都是Ⅱ-Ⅵ族宽禁带半导体材料，它们的禁带宽度分别为 3.37eV（纤锌 矿结构）和 3.66eV（闪锌矿结构）。由于 S 原子和 O 原子之间具有较大的电负性和尺寸差 异，在氧化锌中引入