铂基三元合金制备及其光学性质研究.doc

  铂基三元合金制备及其光学性质研究# 赵海东，杨文波，杨生春，丁秉钧** （西安交通大学理学院，西安 710049） 5 10 摘要：本文首先制备了金-银二元合金纳米胶体。然后以制备得到的金-银二元合金 Ag4Au 纳 米胶体为前驱体，加入氯铂酸，利用银和铂离子之间的置换反应制备出一系列铂含量不同的 铂-银-金三元合金纳米胶体。紫外吸收光谱测试结果表明，铂-银-金三元合金纳米胶体的最 大吸收峰波长介于 Ag4Au（414 nm）和 PtAu（436 nm）的最大吸收峰之间，而且这些合金 都有且仅有一个吸收峰，表明产物为均相三元合金。同时铂-银-金三元合金最大吸收峰波长 与 Pt/(Pt+Au)物质的量比呈线性关系，随铂含量增加最大吸收峰波长向长波方向移动。TEM 结果表明合金产物胶体颗粒分布均匀，基本无团聚现象，平均粒径在 8-10 nm 之间。HRTEM 结果中出现的晶面间距 0.232 nm 和 0.204 nm 分别与合金的（111）和（200）晶面对应。 关键词：合金；金-银二元合金；铂-银-金三元合金；胶体 中图分类号：TB383 15 The Synthesis and Optical Properties of Pt Based Tri-metallic Alloy Zhao Haidong, Yang Wenbo, Yang Shengchun, Ding Bingjun (School of Science, Xian Jiaotong University, Xi’an 710049) 20 25 30 35 40 Abstract: In this paper, we aimed to develop a simple method for the preparation of Pt based tri-metallic alloys. Firstly, the Au-Ag bi-metallic alloys were synthesised by co-reduction method, then, using the as-prepared alloy of Ag4Au and chloroplatinic acid as the precursor, a variety of Pt-Ag-Au tri-metallic alloys were obtained through the replacement reaction. UV absorption spectrum results show that the maximum absorption wavelength of the Pt-Ag-Au tri-metallic alloys range between Ag4Au (414 nm) and PtAu (436 nm). And, these alloys have only one absorption peak suggesting the product are homogeneous ternary alloy, rather than a simple mixture of metal. Meanwhile, the maximum absorption wavelength of the Pt-Ag-Au tri-metallic alloys were linear with the molar ratio of Pt/(Pt + Au), and the maximum absorption wavelength would move to long wave with the incresing of the molar ratio. The TEM results showed that the alloy product were uniform nanoparticles, and the average size were between 8 and 10 nm. The lattice fringes correspond to the spacing of 0.232 and 0.204 nm, which match well with the expected d-spacings of the (111) and (200) plane of the alloy, respectively. Keywords: alloy; Au-Ag bi-metallic; Pt-Ag-Au tri-metallic; colloid 0 引言 贵金属合金因其在光学、催化、生物和微电子等领域具有重要的应用，近年来越来越受 到重视[1]，其中