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Evolution of Electromagnetic and Mechnical Properties of
Co-rich Amorphous Alloys under Field Annealing#
SONG Yujun1, SUN Qiangqiang1, TANG Zhaowei1, ZHANG Tao1, JIANG Yanwei2*
5
10
15
20
25
(1. Key Laboratory of Aerospace Materials and Performance, School of Materials Science and
Engineering, Beihang University, Beijing 100191;
2. Key Laboratory of Fundamental Science for National Defense of Novel Inertial Instrument
Navigation System Technology, Beihang University, Beijing 100191)
Abstract: Microstructure changes of the cross-section of Co-rich amorphous ribbons
(Co68.15Fe4.35Si12.5B15, atomic%) annealed at 450°C for 30 minutes with a 10 Oe longitudinal or
transverse external magnetic field have investigated by comparing with those as spun and annealed
samples without field. The ribbons annealed under the transverse field exhibit an extremely distinct
gradient microstructure across the section of the ribbon (gradient nano-amorphous ribbons), featured
with the amorphous-phased skin layers (top and bottom) of about 4-5 μm and one middle crystalline
layer of about 10-12μm having the grain size of 434 ± 99 nm. While the ribbons annealed under the
longitudinal field are featured by formation of primary nanocrystals with size of 2.5 ± 0.4 nm and
inter-grain spacing of 2.0 ± 0.5 nm almost uniform dispersing in the amorphous residues
(nano-amorphous ribbons). These kinds of amorphous-nanostructural composites preserve unique
magnetic properties and enhanced conductivities by comparing with those as-spun ribbons or annealed
ribbons without field, leading to excellent giant magneto-impedance (GMI) effects. Particularly, the
nano-amorphous ribbons lose the dual-peak feature as the as-spun ribbons but a mono GMI peak, and
preserve a maximum MI ratio of 520 % at a given frequency of 10MHz and the maximum field of
40Oe. While the gradient nano-amorphous ribbons still show dual-peak feature as the as-spun ribbons,
preserve a sensitivity of 200 %/Oe at the low magnetic fi
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