MgO-Al2O3-SiO2系微晶玻璃晶化行为和力学性能.pdfVIP

·24 · 材料导报网刊 2006 年 4 月第 2 期 MgO-Al O -SiO 系微晶玻璃晶化行为和力学性能 2 3 2 曹高辉,刘立强,李真一 ( 山东科技大学材料科学与工程学院，青岛 266510) 摘要 采用差热分析、X 射线衍射分析和扫描电镜观察等测试方法，对以TiO 和ZrO 作为复合晶核剂生成的微晶玻璃 2 2 的晶化行为进行了研究，并讨论了热处理工艺与晶化行为、力学性能之间的关系。结果表明:随温度升高，玻璃中依次析出 镁铝钛酸盐、假蓝宝石、尖晶石、α-堇青石、顽火辉石等晶体。材料力学性能取决于热处理工艺，经800℃、2h 和1190℃， 1h 处理后，所制备的陶瓷试样具有良好的力学性能，抗弯强度可稳定在320MPa 以上。 关键词 微晶玻璃 晶化 TiO2\ZrO2 力学性能 Crystallization and Mechanical Properties of MgO-Al O -SiO Glass-ceramic 2 3 2 CAO Gaohui，LIU Liqiang ，LI Zhenyi (College of Material Science and Engeering，Shan Dong University of Science and Technology,Qing Dao 266510) Abstract Crystallization process of glass-ceramic containing TiO and ZrO as nucleating agents is studied by DTA, XRD, 2 2 SEM techniques and the mechanical properties are tested as well. The relationships between heat treatment methods and crystalline types, mechanical properties are also discussed. The result shows that with the increasing temperature, MAT, sapphirine, spinel, α-cordierite, enstatite are precipitated in glass in sequence. Mechanical properties of this material mainly depend on heat treatment methods. When the glass is heated at 800 ℃ for 2h and then at 1190 ℃ for 1h, excellent mechanical properties can be obtained and its flexural strength can reach to over 320MPa steadily. Key words glass-ceramic,crystallization,titamoc oxide\zirconium oxide,mechanical properties 铝硅酸盐微晶玻璃具有机械强度高、耐磨损、耐腐蚀等 有衍射实验保持相同条件:扫描电压为 40kV ，电流为 50mA， 特性，它在机械、建筑和化学工业上具有广阔的应用前景。