烃类转化制CO工艺蒸汽冷凝液回用研究.docVIP

化学化工学院 毕业论文(设计) (2013年) 课题名称 烃类转化制CO工艺蒸汽 冷凝液回用研究 学生姓名 李博 学 号 1001090516 指导教师 王海燕 南京工业大学化学化工学院 制 烃类转化制CO工艺蒸汽冷凝液回用研究 摘 要 天然气裂解制CO合成气过程中，为充分利用原料，防止催化剂结焦，需要加入大量的水蒸汽，这些水蒸汽逐级冷凝后生成工艺冷凝液。冷凝液中含有少量低分子有机物和金属离子，不能直接作为锅炉水回用；其中一部分经过汽提后仅作循环水使用，剩余部分被直接排放，造成资源浪费和环境污染。 本文以AC-1为吸附剂，采用吸附分离工艺，考察了工艺冷凝液中总碳总氮在AC-1上的吸附等温线和吸附速率；在实验室自制吸附装置上考察了吸附温度、液相进料空速等操作条件对AC-1吸附总碳、总氮穿透吸附量的影响。实验结果表明，在吸附温度为80℃，液固比为300条件下，AC-1对总碳的平衡吸附量达到1.8mg/g，对总氮的平衡吸附量达到2.3mg/g；在吸附温度80℃，液相进料空速为5.44h-1条件下，吸附处理后的冷凝液总碳含量可以从70ppm下降到10ppm, 总氮含量可以从50ppm下降到5ppm, 电导率下降了75%以上，pH上升到7左右，AC-1 不仅可以有效的去除冷凝液中的TOC和TN而且还能够大幅降低冷凝液的离子含量吸附后的冷凝液稍加处理有就可以达到锅炉给水的水质要求 Study on the reuse of syngas process condensate by adsorption ABSTRACT In order to make full use of the raw material and prevent catalyst coking in the process of syngas production by methane cracking, a larger amount of steam is need. The overabundance steam then produce condensate. The condensate water contains part of CO2 and a small amount of metal ion causing steam quality unqualified and can not be used as boiler water. The traditional method is to use it as circulating water after stripping, some even emissions directly, resulting in a waste of resources and environmental pollution. In this paper AC-1with rich micropores and acidic functional groups as adsorbent is used for adsorbing of syngas condensate water to reuse it as boiler water. The effects of different adsorption temperature, liquid-solid ratio, liquid feed space velocity conditions on the carbon and nitrogen adsorption capacity of AC-1 was investigated. The static experimental results show that the total carbon equilibrium adsorption capacity can reach 1.8mg/g and the total nitrogen equilibrium adsorption capacity can reach 2.3mg/g. The dynamic experimental results show that the AC-1 is very efficient for the removal of carbon and nitrogen compounds, the carbon content can be