磷石膏分解特性对磷石膏制硫酸联产水泥新工艺的影响研究.pdfVIP

35 4 () http: / /www. kustjourna.l com / V o.l 35 N o4 20 10 8 Journal ofK unm ing U n iversity of Science and T echnology ( Science and T echnology Aug. 20 10 do:i 10. 3969 / j. issn. 1007- 855x. 2010. 04. 017 余 苏, 李建锡, 马丽萍, 舒艺周, 唐霜露, 卢凯芳, 张 平, 曹盈盈 ( , 650093 : 磷石膏预分解制硫酸联产水泥技术的关键是对磷石膏分解特性的深入了解, 结合水泥新 型干法预分解 的特点, 采用热分析及相关试验对磷石膏的热分解性能进行了研究. 结果表明, 磷石膏完全分解温度在 1 300 以上, 在还原条件下其分解温度也在 1 200 以上. 结果还表明, 由于磷石膏的分解温度往往高于该系统的最低共熔点温度, 其对预热器分解炉的适应性较差, 易 对 系统造成粘结堵塞问题. 利用水泥新型干法技术分解磷石膏制酸并联产水泥的实施会有较 大难度. : 磷石膏; 预热分解 ; 热分析; 粘结堵塞 : O627. 51 : A : 1007- 855X ( 2010 04 - 0080 - 05 Thermal Effects of Phosphogypsum on Co- Production of Acid and Cement YU Su, L I J ai nx,i MA Li p ing, SHU Y izhou, TA NG Shuanglu, LU Ka ifang, ZHANG P ing, CAO Y ingy ing ( F aculty o f M ater ia ls Sc ience and Eng inee ring, K unm ing U niversity of Science and T echno logy, Kunm ing 650093, Ch ina A stract: The key in acid and cem ent co- product ion by use o f phosphogypsum w ith the new dry cem en t tech nology is to deep ly learn the decomposition character o f phosphogyp sum. In th is paper, studies have been m ade in the decom position perfo rm ance of phosphogyp sum w ith the therm al ana lysis and the analysis o f the cem ent new dry techno logy. The results show that the fulfilled decom position tem perature o f phosphogypsum is about 1 300 , and even in the restore condition, the tem perature is above 1 200 . It a lso show s that the flex ib ility of the precalc iner and the preheater in cem ent techno logy for the phosphogyp sum is not so good, and it can easily resu lt in bond ing and jamm ing in the cem ent k iln system, ow ing to the fact that the decom position tem perature of phosphogyp sum is h igher than its