分散相粒径对油水乳状液蜡沉积的影响.docVIP

输送工艺  2013 年 2 月　第 32 卷 第 2 期  文章编号：1000-8241（2013）02-0152-05 分散相粒径对油水乳状液蜡沉积的影响  张宇1  于达2 王鹏宇2  段纪淼2 王亮3 王磊3 1. 中国石油集团东南亚管道有限公司，北京 100028；2. 中国石油大学（北京）石油工程教育部重点实验室 · 城市油气输配 技术北京市重点实验室，北京 102249；3. 中国石化集团国际石油勘探开发有限公司，北京 100029 摘要：利用冷指实验装置，针对油包水型乳状液分散相粒径大小及分布，对油水体系中蜡沉积规律的 影响进行实验研究，结果表明：在相同的搅拌时间下，随着配制乳状液时搅拌速率的增大，分散相中 小液滴的数量增多，大液滴的数量减少；在相同的含水率下，随着乳状液体系中分散相液滴直径的减 小和小液滴数量的增多，蜡沉积速率减小。对沉积物组分进行了高温气相色谱（HTGC）分析，指出 在相同的实验时间条件下，油包水型乳状液分散相粒径大小及分布仅对蜡沉积层厚度有显著影响， 对沉积层中蜡质量分数的影响可以忽略不计。该研究成果为进一步研究油水流动条件下的蜡沉积 特性奠定了基础。（图 5，参 12） 关键词：含蜡原油；蜡沉积；分散相；粒径大小；粒径分布；乳状液 中图分类号：TE83　　　　　 文献标识码：A　　　　　 doi：10.6047/j.issn.1000-8241.2013.02.008 Influence of particle size of dispersed phase on oil-water emulsion wax deposition Zhang Yu1,Yu Da2, Wang Pengyu2, Duan Jimiao2, Wang Liang3, Wang Lei3 1. CNPC South East Asia Pipeline Company Limited, Beijing, 100028; 2. Beijing Key Laboratory of Urban Oil and Gas Distribution Technology, China University of Petroleum (Beijing), Beijing, 102249; 3. SINOPEC International Exploration and Production Corporation, Beijing, 100029 Abstract: A cold finger experiment is carried out to study the influence of particle size and distribution of dispersed phase of water-in-oil emulsions on wax deposition law in the oil and water system. The results show that when the stirring time remain unchanged, with the increase in the stirring rate in preparing emulsion, the number of small liquid droplets in dispersed phase increases, while the number of big liquid droplets decreases. When the water cut remains unchanged, with the reduction in the diameter of the dispersed droplets in the emulsion system and the increase in the number of small liquid droplets, the wax deposition rate decreases. The high-temperature gas chromatography (HTGC) analysis of sediment components shows that under the condition of same experiment time, dispersed phase particle size and distribution of water-in-oil emulsion only have a significant effect on the thickness of the wax deposited layer, but has