改性香菇培养基废料对模拟矿山酸性废水中Cu 2 的吸附.docVIP

第 44 卷第 7 期 2013 年 7 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.44 No.7 July 2013  改性香菇培养基废料对模拟矿山酸性废水中 Cu 2+ 的吸附 陈月芳 1, 2 ，曹丽霞 1 ，林海 1 ，董颖博 1 ，霍汉鑫 1 ，程皝 1 (1. 北京科技大学土木与环境工程学院，北京，100083； 2. Norwegian University of Science and Technology, Trondheim 7491) 摘要：采用碱+微波辅助磷酸酯化法对天然香菇培养基废料进行改性，制得改性香菇培养基废料(MSSS)，并对其 进行红外光谱分析。考察 MSSS 对模拟矿山酸性废水中较高浓度 Cu 2+ 的吸附动力学、吸附等温线以及溶液 pH 对 吸附的影响，并对吸附饱和的 MSSS 进行焚烧处理试验。实验结果表明：改性处理使香菇培养基废料官能团数目 及种类增多，吸附性能提高；MSSS 对 Cu 2+ 的吸附量随着 pH 的升高而增大，在 pH 为 0.7 左右时，其对 Cu 2+ 的吸 附量达到 2.95 mg/g；吸附过程很好地拟合拟二级动力学模型；吸附等温线符合 Langmuir 方程, 在 pH 为 3 时，最 大吸附量为 24.33 mg/g；焚烧后残渣中铜含量为 92.48 mg/g，富集 7.07 倍。 关键词：改性香菇培养基废料；吸附；矿山酸性废水；Cu 2+ ；焚烧 中图分类号：X703.1 文献标志码：A 文章编号：1672?7207(2013)07?3080?06  Biosorption of Cu 2+ from simulated acid mine drainage by modified spent shiitake substrate CHEN Yuefang 1, 2 , CAO Lixia 1 , LIN Hai 1 , DONG Yingbo 1 , HUO Hanxin 1 , CHENG Huang 1 (1. School of Civil and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China? 2. Norwegian University of Science and Technology, Trondheim 7491, Norway) Abstract: NaOH combining microwave-assisted phosphorylation was used to modify natural spent shiitake substrate and the product was named modified spent shiitake substrate (MSSS), which was characterized by infrared spectroscopy. Adsorption kinetics, equilibrium isotherm of MSSS adsorbing Cu 2+ from simulated acid mine drainage and effect of solution pH on biosorption were investigated. Biosorption saturation MSSS was combusted. The results show that the modification increases the number and types of active functional groups, thus biosorption properties are enhanced. Biosorption capacity increases with the increase of the solution pH rising? while solution pH value is about 0.7, the biosorption capacity reaches 2.95 mg/g. The biosorption process follows pseudo-