干馏松焦油在钙基催化剂作用下的裂解燃烧特性.docVIP

第 44 卷第 3 期 2013 年 3 月  中南大学学报(自然科学版) Journal of Central South University (Science and Technology)  Vol.44 No.3 Mar. 2013  干馏松焦油在钙基催化剂作用下的裂解燃烧特性 刘波 1 ，时章明 1 ，何金桥 2 ，肖波 2 (1. 中南大学能源科学与工程学院，湖南长沙，410083； 2. 长沙理工大学能源与动力工程学院，湖南长沙，410076) 摘要：为提高耐火材料组分的焦油催化裂解作用，对松焦油与不同钙基催化剂添加物试样进行燃烧条件下的热重 实验，并对催化剂作用下焦油的组分、着火性、稳燃及燃尽性进行分析。研究结果表明：钙基催化剂不能改善干 馏松焦油的着火性，但对焦油具有良好的催化重整作用，使得干馏松焦油的燃尽特性指数由 46.85×10 ?4 min ?1 迅 速下降到(20.73~24.12)×10 ?4 min ?1 ；燃烧生成的 CO2 与 CaO 的作用有利于促进燃烧，CaCO3 则促进了焦油中重 质烃成分与轻质烃成分中碳元素的交换，使焦油组分更趋一致。 关键词：焦油；生物质；热重分析；催化剂；燃烧特性 中图分类号：TK6；TK224.2 文献标志码：A 文章编号：1672?7207(2013)03?1235?05  Decomposition and combustion characteristics of dry distillation pine tar with calcium-based catalyst LIU Bo 1 , SHI Zhangming 1 , HE Jinqiao 2 , XIAO Bo 2 (1. School of Energy Science and Engineering, Central South University, Changsha 410083, China? 2. Institute of Energy Power Engineering, Changsha University of Science and Technology, Changsha 410076, China) Abstract: In order to study the combustion characteristics of pine tar under calcium-based catalyst, the samples of pine tar and different calcium-based catalysts were investigated by thermogravimetric analyzer (TGA), and the samples’ properties of components, ignitability, stable-combustion ability and burnedout were studied. The results show that calcium-based catalyst cannot improve the ignitability of dry distillation pine tar, but it has good catalytic reforming role to tar, and can make the burnedout characteristic index of dry distillation pine tar fall rapidly from 46.85×10 ?4 min ?1 to (20.73?24.12)×10 ?4 min ?1 . The effect between CaO and CO2 creating during combustion is in favour of tar burning. CaCO3 promotes the exchange of carbon element between the heavier hydrocarbon and the light hydrocarbon, and makes tar components more uniform. Key words: tar? biomass? thermogravimetric analysis? catalyst? combustion characteristic  生物质是继煤炭和石油之后的世界第三大主