一种制备膨胀石墨的新方法及其压制品的性能研究.pdfVIP

156 / 2007 1( China SAMP E2007 A N ovel Way to Fabricate Expanded Gr aphite and the Performance for it s flexible Graphite , , , , ( , , 030001 WEI Xing2hai, LIU Lang, ZH ANG Jin2xi, SH I Jing2li, GUO Quan2gui ( Key Laboratory of Car bon Mat er ial, Chinese Academy of Sciences, In st itut e of Coal Chemistr y, T aiyuan 030001, China : 01 5mm , , 72% ( 1~ 3min1 , 900 , 549mL/ g , : ( T ( Q ( d , T= 121 1d2 71 6, R= 01 977; Q= 231 97d+ 111 9, R = 01 968 : ; ; ; : A : 100 12438 1( 2007 Supp2l 0 1562 04 Abstr act : Natur al flake graphite with p art icle size of ca 01 5mm and p erchloric acid with variou s con2 centrat ion ranging from 20%272% ( m ass fracfion wer e u sed as host m at erial and oxidating/ int er cala2 t ing agent s resp ect ively t o fabricat e expanded gr aphit e by direct thermooxidative conversion m ethod1 The exp anded volum e of flake graphit e increases with the concentrat ion of perchlor ic acid increasing1 The exp anded volume of flake graphite which was first impregnat ed by p er chloric acid with the con2 centrat ion of 72% for 1~ 3 min1 and then exfoliated at 900 was 549 mL/ g1 T he mechanical, electri2 cal, thermal performances of flexible graphit e with defer ent densities manu factured with the exp anded graphit e with expanded volume of 549 mL/ g were charact erized by all2purpose m at erial t est er , mi2 croohmmeter and laser thermal flash2m et er1 T he results show that t en sile str ength ( T , electrical re2 sist ivity( Q have posit ive linear relat ion ship with densities, respectively: T = 121 1d271 6 ( relat ionship coefficien