硝基清漆膜厚度对硝基清漆VOCs释放的影响.pdfVIP

中国环境科学 2009,29(8) ：790~794 China Environmental Science 硝基清漆膜厚度对硝基清漆 VOCs 释放的影响 1,2 1* 1 2 王立鑫 ,刘兆荣 , 白郁华 ,张寅平 (1.北京大学环境科学与工程学院,北京 100871 ；2.清华大学建筑学院, 北京 100084) 摘要：利用自制的小型环境测试舱,研究了硝基清漆膜厚度对挥发性有机物(VOCs)释放的影响.漆膜厚度分别为 296,508,715,799,960µm,测试条 3 件为:温度为 25.0℃,相对湿度为 23.9%,空气流量为0.75m /h,空气流速为3.4cm/s,支持板为不锈钢盘.采用真空采样罐采集舱出口空气,用气相色谱 (GC-FID)分析测试.确定了 5 种主要 VOCs( 甲基环乙烷、甲苯、乙苯、间/对二甲苯和邻二甲苯)的浓度,并以一阶衰减模型对浓度进行模拟计算 得到释放速率.结果表明,漆膜厚度并不影响 VOCs 的峰值浓度和初始释放速率,但漆膜越厚,VOCs 的浓度衰减越慢,衰减速率越小. 关键词：硝基清漆；VOCs ；漆膜厚度；环境测试舱 中图分类号：X501 文献标识码：A 文章编号：1000-6923(2009)08-0790-05 Effect of paint film thickness on VOCs emission from nitrocellulose varnish. WANG Li-xin 1, 2, LIU Zhao-rong1*, BAI Yu-hua1, ZHANG Yin-ping2 (1.College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China；2.School of Architecture, Tsinghua University, Beijing 100084, China). China Environmental Science, 2009,29(8) ：790~794 Abstract ：The effect of the paint film thickness on the emission of volatile organic compounds (VOCs) from nitrocellulose varnishes was studied in the self-made small-scale dynamic environmental test chamber. The film thickness range was 296, 508, 715, 799 and 960µm in turn. In all the experiments the temperature, the relative humidity, the airflow rate and the airflow velocity were set to 25.0℃, 23.9%, 0.75m3/h and 3.4cm/s respectively. The substrate used was stainless steel plate. The air samples were collected using vacuum canisters at the outlet of the chamber. And the sample was analyzed by the gas chromatography (GC-FID) shortly. The concentrations of five major VOCs including methyl cyclohexane, toluene, ethylbenzene, p, x-xylene and o-xylene were determined. The emission rates of VOCs were calculated through the first-order decay m