非均匀体系介电研究的现状与展望3.pdfVIP

第 9 卷 第 4 期 化　学　进　展 V o l. 9 N o. 4 1997 年 12 月 PRO GR ESS IN CH EM ISTR Y D ec. , 1997 非均匀体系介电研究的现状与展望 赵孔双 ( 厦门大学化学系　固体表面物理化学国家重点实验室　厦门 361005) 摘　要　用介电谱方法讨论化学中的非均匀体系是近十几年发展起来的交叉性新领 域, 它在分散体系、高分子膜以及生物细胞体系的研究中占有重要地位。本文从理论和应用 两方面综述该领域的发展过程及研究现状, 并结合实例阐述了构造和介电弛豫模式的关系 以及该方法的特点。在对遗留问题和最新进展给予评述性讨论的同时, 指出了进一步的研究 方向。 关键词　非均匀体系　介电弛豫　乳状液　生物细胞　高分子膜 Presen t Situa tion and Prospects of D ielectr ic Study on Heterogeneous System s Z hao K ong shuang (State Key L abo rato ry fo r Physical Chem istry of So lid Su rface, D epartm en t of Chem istry, X iam en U n iversity , X iam en 361005, Ch ina) 　 ( ) Abstract D ielectric spectro scopy m ethod D SM fo r studying chem istry system s w ith 10 . heterogeneou s structu re is an in terdiscip linary area developed in recen t years T he m ethod is very im po rtan t in the studies fo r disperse system s, m em b ranes and b io logical . cells system s T h is paper review s the h isto ry and cu rren t research on the D SM fo r hetero . geneou s system s in bo th theo retical and p ractical aspects In p resen ting the featu res of the m ethod , the em phases are laid on the relation betw een the structu res of heterogeneou s system s and relaxation pattern s w ith exam p les illu strated. T he p rob lem s rem ained and re cen t p rogress are in troduced, and som e research aspects fo r fu rther w o rk are p ropo sed. Key words　heterogeneou s system s; dielectric relaxation; em u lsion; b io log