通过共挤出来制备交替多层的复合材料.docVIP

共挤出制备交替多层高分子复合材料 王明 郭少云* 李姜 沈佳斌 许双禧 （高分子材料与工程国家重点实验室四川大学高分子研究所，四川，成都，610065) 近年来，W.J.Shrenck[1]、A.Hiltner[]等人用共挤出的方法制备了几十到几千层的交替多层高分子复合材料。这类材料不仅同时具有两种不同聚合物材料的优良特性，而且还会产生协同效应，使其在力学性能、阻隔性能、光学性能、导电性能等方面具有独特之处。另外，此种材料为扩散、粘接、结晶等基础理论研究提供了很好的模型本实验室自主开发了一套共挤出体系，如图1所示，高分子熔体从两台挤出机经过不同的流道在连接器（feed block）出口处合并成一股两层的熔体，然后进入分层单元（multiplying element）分层单元增加层数图2在牵引装置的下，多层复合材料经过冷却装置被牵引出分层单元。交替多层结构复合材料在很多性能上不同于普通共混的材料，例如图所示，PS/EPDM普通共混材料为不透明的，而相应的PS/EPDM多层复合材料为透明的。 Figure 1 Schematic representation of the micro-layer co-extrusion system. Figure 2 It illustrates how two multiplying elements multiply the number of layers from 2 to 8. Two-layer polymer melt stream from the feed block flows through a series of multiplying elements: each element splits the melt vertically, spreads it horizontally, and finally recombines it to twice the number of layers. PA/HDPE 32 layers PS/EPDM 64 layers Figure 3 SEM micrographs of the composites obtained by the co-extruder system. For PA/HDPE 32 layers composite, formic acid was used to etch the PA. For PS/EPDM 64 layers composite, butanone was used to etch the PS. PS/EPDM (conventional compound) PS/EPDM (64 layers composite) Figure 4 Photograghs of the 64-layer composite and the conventional compound. Both composites contain 28% EPDM, and the total thickness of both sheets is ca. 1.5mm. 参考文献 T. Alfrey, Jr., W.J. Schrenk Multipolymer Systems. Science, 1980, 208(4446), 813 R.Y.F. Liu, T.E. Bernal-Lara, A. Hiltner, E. Baer. Polymer Interphase Materials by Forced Assembly. Macromolecules, 2005, 38(11), 4819 Preparing Alternative Multilayer Composites by Co-extrusion Wang Ming Guo Shaoyun* Li Jiang Shen Jiabin Xu Shuangxi ( Polymer Research Institute of Sichuan university, The State Key Laboratory of Polymer Materials Engineering, Chengdu, Sichuan, 610065 ) Abstract: A multilayer co-extrusion system was designed by our laboratory. The system contains two extruders, feed block, multiplying e