浸渍相转化法制备陶瓷中空纤维膜的研究进展.pdfVIP

第27 卷 第7 期 无 机 材 料 学 报 Vol. 27 No. 7 2012 年7 月 Journal of Inorganic Materials Jul., 2012 文章编号: 1000-324X(2012)07-0673-07 DOI: 10.3724/SP.J.1077.2012.11689 浸渍相转化法制备陶瓷中空纤维膜的研究进展 刘朋超, 马敬红, 杨曙光, 龚静华, 徐 坚 ( 东华大学 材料科学与工程学院, 纤维材料改性国家重点实验室, 上海 201620) 摘 要: 浸渍相转化法可以制备非对称结构的陶瓷中空纤维膜. 本文讨论了陶瓷中空纤维膜的发展情况, 并着重探 讨了各因素对膜孔结构的影响. 大量陶瓷粉体存在情况下的相转化机理, 孔结构与力学强度的平衡问题, 是目前 需要重点关注的两个问题. 有效调节孔结构, 保证其力学性能可以实现陶瓷中空纤维膜在分离和纯化、固体氧化物 燃料电池、膜催化器和膜反应器等方面的广泛应用. 关 键 词: 浸渍相转化法; 陶瓷; 中空纤维膜; 综述 中图分类号: TQ028 文献标识码: A Research Progress on the Preparation of Ceramic Hollow Fiber Membranes by Nonsolvent Induced Phase Separation LIU Peng-Chao, MA Jing-Hong, YANG Shu-Guang, GONG Jing-Hua, XU Jian (State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineer- ing, Donghua University, Shanghai 201620, China) Abstract: Ceramic hollow fiber membranes (CHFM) with an asymmetric structure can be fabricated by the method nonsolvent induced phase separation (NIPS). The paper reviews the progress and tendency of the ceramic hollow fiber membranes using NIPS technic, especially on the influence of factors on the structure of hollow membranes. The dis- cussion on the mechanism of phase inversion in the systems containing much ceramic powders, with the balance be- tween porous structure and mechanical strength, are two important issues of requiring concern. Through structure’s controlled effectively and mechanical strength preserved, hollow fiber membranes c