相变材料微胶囊的制备及应用.pdfVIP

第30 卷 第1 期 天 津 工 业 大 学 学 报 Vol.30 No.1 圆园11 年2 月 韵哉砸晕粤蕴 韵云 栽陨粤晕 陨晕 孕韵蕴再栽耘悦匀晕陨悦 哉晕陨灾耘砸杂陨栽再 February 2011 变材料微胶囊的制备及应用 1 2 3 虹霞 ，李和玉 ，张健飞 1. 天津工业大学 环境与化学工程学院，天津 300160；2. 天津工业大学 功能纤维研究所，天津 300160 ；3. 天 津工业大学 纺织学院，天津 300160） 摘 要： 用原位聚合法合成了以正十八烷为囊芯、三聚氰胺- 甲醛树脂为囊壁的相变材料微胶囊，并用其对棉织 物进行了整理. 用扫描电镜、激光粒度仪对微胶囊及整理后织物的形貌、粒度进行表征，并对微胶囊及整理 后织物的热性能进行了研究. 结果表明：微胶囊粒径小，粒径分布窄，具有较高的相变焓；整理后织物具有蓄 热调温功能. 关键词：相变材料；微胶囊；纺织品整理 中图分类号：TS102.528 文献标志码：A 文章编号：远苑 原园圆源载 圆园11）园1原园园12原园4 Preparation and application of microcapsules containing phase change materials 1 2 3 CAO Hong-xia ，LI He-yu ，ZHANG Jian-fei 1. School of Environmental and Chemical Engineering ，Tianj in Polytechnic University ，Tianj in 300160 ，China ；2. Insti原 tute of Functional Fibers ，Tianji n Polytechnic Unirersity ，Tianji n 300160 ，China ；3. School of Textiles ，Tianj in Polytech原 nic University ，Tianj in 300160 ，China ） Abstract ：The phase change microcapsules with n-octadecane as core and melamine -formaldehyde as shell were pre鄄 pared by in situ polymerization. The fabrics were finished with the microcapsules. The morphology of micro鄄 capsules and finished fabrics were characterized by using scanning electron microscopy 渊SEM冤曰 the diameter distributions of the microcapsules were investigated by particle size analyzer 曰 the thermal physical properties of microcapsules and finished fabrics were analyzed by thermal an