金纳米线介孔二氧化硅薄膜的制备和非线性光学性能研究.pdfVIP

第28 卷 第 10 期 无 机 材 料 学 报 Vol. 28 No. 10 2013 年10 月 Journal of Inorganic Materials Oct., 2013 文章编号: 1000-324X(2013)10-1087-06 DOI: 10.3724/SP.J.1077.2013.12782 金纳米线−介孔二氧化硅薄膜的制备和非线性光学性能研究 张 倩, 单 锋, 陆学民, 路庆华 (上海交通大学 化学化工学院, 上海 200240) 摘 要: 利用热气流法制备的宏观平行取向介孔二氧化硅薄膜为载体, 经氨基硅烷 APTS 对孔道进行表面修饰后, 在介孔孔道中原位生成了金纳米线。研究结果表明: 由于介孔孔道的限制效应, 在氯金酸的乙醇溶液中浸泡较长时 间后, 利用氢气还原可获得长径比较大的金纳米线。Z 扫描测试表明, 这种金纳米线-介孔二氧化硅复合薄膜材料具有 明显的非线性光学特性。在532 nm 的激光下, 它还表现出明显的各向异性, 有望在新型光学器件方面得到应用。 关 键 词: 介孔二氧化硅; 金纳米线; 非线性光学; 取向 中图分类号: O612; O484 文献标识码: A Preparation and Non-linear Optical Properties of Mesoporous Silica Film Incorporated with Gold Nanowires ZHANG Qian, SHAN Feng, LU Xue-Min, LU Qing-Hua (School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China) Abstract: An Au-loaded oriented mesoporous silica film was prepared by hot air flow method and its non-linear op- tical properties were investigated. Amino groups were first introduced to the oriented mesochannels’ surface based on a chemical reaction, and gold nanowires were incorporated into the oriented mesochannels via the reduction by H2 af- ter the interaction between the amino groups and auric chloride acid. The hybrid film presents obviously non-linear optical properties according to Z-scan measurement. The hybrid film shows anisotropy, which is consistent with the fact that the nanowires are aligned. So the film is expected to be applied in the new optical devices. Key words: mesoporous silica film; gold nanowires; non-linear