ZnO添加对MgTiO3陶瓷的烧结及微波介电性能的影响.pdf

第 30 卷 第 10 期电子 元件 与材料Vol.30 No.10 2011 年 10 月 ELECTRONIC COMPONENTS AND MATERIALS Oct. 2011 研究与试 制 ZnO 添加对 MgTiO 陶瓷的烧结及微波 3 介电性能的影响 1 1 1 1 2 徐岩岩 ,傅仁利 ,李 冉 ,顾席光 ,韩 巍 1. 南京航空航天大学 材料科学与技术学院,江苏 南京 210016;2. 广东风华高新科技股份有限公司 技术中 心,广东 肇庆 526020 摘要: 采用传统固相反应法制备了 Mg Zn TiO MZT微波介质陶瓷,研究了添加 ZnO对 MgTiO 陶瓷的烧 0.95 0.05 3 3 结过程及介电性能的影响。结果表明,添加 ZnO不仅有效降低了 MgTiO 陶瓷的烧结温度,提高了陶瓷的致密度, 3 而且有效抑制了中间相 MgTi O 的产生,提高了 MgTiO 陶瓷的微波介电性能。当 ZnO 添加量为摩尔分数 5%时, 2 5 3 在 1 300 ℃烧结 4 h所制 MZT陶瓷的物相组成为 Mg Zn TiO ,相对密度为 96.4%,介电性能为:相对介电常数 0.95 0.05 3 ?6 ε 19.0,品质因数 Q?f 27 508 GHz7.8 GHz,频率温度系数 τ ?16×10 / ℃。 r关键词: MgTiO ;烧结;ZnO;微波介电性能 3 中图分类号: TM28 文献标识码:A 文章编号:1001-2028 (2011)10-0011-04 Effects of ZnO additive on sintering behavior and microwave dielectric properties of MgTiO ceramics 3 1 1 1 1 2 XU Yanyan , FU Renli , LI Ran , GU Xiguang , HAN Wei 1.College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China; 2. Fenghua Advanced Technology Holding Co., Ltd, Zhaoqing 526020,Guangdong Province, China Abstract: Mg Zn TiO MZT microwave dielectric ceramics were prepared by conventional solid state method0.95 0.05 3 The effects of ZnO additive on the sintering process and dielectric properties of MgTiO ceramics were investigated. The 3 results show that the sintering temperature of MgTiO ceramics can be lowed, and the densification of MgTiO ceramics 3 3 can be improved through the addition of ZnO. Moreover, the ZnO additives can effectively restrain the formation of intermediate phase MgTi O , and keep excellent microwave dielectric properties of MgTiO ceramics. The relative density 2 5 3 of prepared MZT ceramic with 5%mole fraction ZnO additive sintered at 1 300 ℃ for 4 h is 96.4%, and the MZT ceramic?6 exhibits the optimum microwave dielectric properties: ε 19.0,Q?f 27 508 GHz7.8 GHz,τ ?16×10 /℃rKey words: MgTiO ; sintering; ZnO; microwave dielectric properties 3随着移动通讯与卫星通讯技术的迅速发展,微 于 MgTiO 材料烧结温度高需 1 430 ℃以上温度烧 3波介质陶瓷作