4种农林生物质热解特性及动力学研究.docVIP

  4 种农林生物质热解特性及动力学研究 樊永胜，蔡忆昔，李小华，赵卫东，俞宁，尹海云 (江苏大学汽车与交通工程学院，江苏镇江 212013) 摘 要：为优化生物质热解工艺，研究了 4 种农林生物质的热解特性及其动力学参数的分布规律。利用热 重分析仪对 4 种生物质的热解失重行为进行了试验研究，采用热解特性指数 P 对生物质的热解特性进行了 综合评价，使用 Coats-Redfern 方法对生物质的热解过程进行了动力学分析。研究结果表明，生物质的热解 反应可分为干燥预热、快速失重和缓慢失重 3 个阶段；各生物质在主热解区低温段所需热解活化能要高于 高温段；活化能和频率因子均随升温速率增大而增大；采用 n=2 级动力学模型能较好的表述整个主热解区 的反应过程；采用 15K/min 的升温速率和 500的热解终温可提高热解反应速率，降低能耗。 关键词：生物质；热重分析；热解特性；动力学；能耗 中图分类号：TK6 文献标识码：A  Pyrolysis characteristics and kinetics of four kinds of agroforestry biomass based on thermo-gravimetric analysis (TGA) Fan Yongsheng，Cai Yixi，Li Xiaohua，Zhao Weidong，Yu Ning，Yin Haiyun (School of Automotive and Traffic Engineering, Jiangsu University, Zhenjiang Jiangsu, China 212013) Abstract: In order to optimize the pyrolysis process, the pyrolysis characteristics and kinetics of four kinds of agricultural and forestry biomass were studied. The thermo-gravimetric experiment was carried out on a thermo-gravimetric analyzer. The pyrolysis characteristics index P was adopted to conduct a comprehensive evaluation of biomass pyrolysis characteristics. The method of Coats-Redfern was used to analyze kinetics of biomass pyrolysis. The results showed that the thermal decomposition process of biomass can be divided into three stages, i.e., drying and preheating, fast Pyrolysis, and slow decomposition of residue. The activation energy of thermal decomposition reaction of biomass in the low temperature stage was higher than that in the high temperature stage. The values of the activation energy and pre-exponential factor increased with the rising heating rate. The thermal decomposition of biomass in the main pyrolysis zone can be effectively described by the kinetic model n = 2. Employing the heating rate of 15 K/min and the temperature of 500℃ can improve the reaction rate and contributes to reducing the energy consumption. Keywords: biomass; thermo-gravimetric analysis (TGA); pyrolysis characteristics; kinetics; energy consumption 0 引言 生物质能源是一种可再生的清洁能源