CH4-H2O-NaCl包裹体V-x参数的准确计算.docVIP

  CH4-H2O-NaCl 包裹体 V-x 参数的准确计算 # 孙睿1，杨诗湘2，王宇平2* 5 10 15 20 25 30 35 40 （1. 大陆动力学国家重点实验室，西北大学地质学系 西安 710069； 2. 西北大学地质学系，西安 710069） 摘要：确定 CH4-H2O-NaCl 包裹体的密度、组成等 V-x 参数有着重要的应用价值，但是传统 的计算方法除测温数据以外还需要目测甲烷气相的体积分数作为计算依据，难免引入较大的 误差。本研究提出了一个无需目测甲烷气相的体积分数，仅以测温数据为依据来准确计算 CH4-H2O-NaCl 包裹体 V-x 参数的新算法。将此新算法与研究者以前建立的相关热力学模型 相结合，开发了能够准确计算不含石盐子晶且甲烷笼合物熔化温度高于冰点温度的 CH4- H2O-NaCl 包裹体 V-x 参数的应用程序。 关键词：地球化学，CH4-H2O-NaCl 体系，流体包裹体，V-x 参数，算法 中图分类号：P59 A new method for calculation of molar volume and bulk composition of CH4-H2O-NaCl fluid inclusions SUN Rui1, YANG Shixiang2, WANG Yuping2 (1. State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xian 710069; 2. Department of Geology, Northwest University, Xian 10069) Abstract: It is important to determine the bulk composition and molar volume (V-x properties) of CH4-H2O-NaCl fluid inclusions for the exploration of ore deposits, oil and natural gases. Traditional method calculates V-x properties of CH4-H2O-NaCl inclusions from micro- thermometric data and the volume fraction of CH4 gas phase. However, the uncertainty in estimation of the volume fraction of fluid inclusions may be large, especially for those inclusions of irregular shape. This study proposed an iterative method to calculate the V-x properties of CH4-H2O-NaCl inclusions from micro-thermometric data (including the final melting temperature of ice, the final melting temperature of CH4 clathrate hydrate, and the total homogenization temperature and homogenization mode of fluid inclusions) only based on the assumption that the bulk composition and the volume of fluid inclusions are constant after entrapped. It is unnecessary to use the volume fraction of CH4 phase as input data for this new method. Combining this method with relevant thermodynamic models developed by us previously, this study also developed a computer program which allows calculation of V-x properties of natural CH4-H2O-NaCl inclusions. Key words: Geochemistry, CH4-H2O-NaCl