Fe-P-B超细非晶合金的制备规律及组元间相互作用研究.pdfVIP

　Vol.21 高 等学校 化学 学 报 No. 1 2 0 0 0 1 C EMICAL JOURNAL OF C INESE UNIVERSIT IES 1013 - - FeP B 1,2 1 1 1 吴　勇 　胡　征　裴华兴　陈　懿 ( 1. , 210093; 2. , 210097) , Fe P B ( 2. 4x 10. 1) . 82 x 18- x - 7 28 , 10. 1% 2. 4%, 8. 7% 13. 1%. , - . Fe P ; ; O643. 13A0251-0790(2000)01-0010-04 -, [ 13] , . , , , , [4] . [2] , Fe, Co, NiB C . Fe-P-B , p [ 1] - - , . - , Fe P B Fe B [5] , - 7 30 , B 23%40% , . , Fe-P-B PB . ( ) ( ) ( ) Mossbauer ICP X XRD Fe-P-B. 1 2.70 3 6 2 ( . . ) 150 , 3. 10 2 2( . . ) 50 , g FeCl O A R mL g Na PO A R mL , 26 g NaCl(A. R. , NaCl ) , - - 7 (A) . 2.65 g KB 4 10 g NaCl 100 mL , - 7 (B) . , ( )10 ( ) , - - . B min A Fe P B 2 , ( . . )( . . ), , 2 C P A R N . , - 4, - 2, 0, 3, 11, 18 28 . ( ) , ICP Mossbauer Mossbauer , 20 57 ( ) , - , mCi Co Pd Fe