高硬水缓蚀阻垢剂TH-658的性能及应用研究.docVIP

新型高硬高碱水缓蚀阻垢剂TH-658B的性能及应用研究 贺茂才，齐晓婧 1，高灿柱2 (1山东省泰和水处理有限公司 山东 枣庄277100；2山东大学环境科学与工程学院，山东 济南250100) 摘要：针对华北、西北等地补充水硬度、碱度高，浓缩后极易引起结垢和腐蚀的难题，开发了高硬、高碱水缓蚀阻垢剂TH-658B。参照标准GB/T 16632-2008进行了静态阻碳酸钙垢试验，参照Q/SY 126-2007标准分别进行了阻碳酸钙垢和硫酸钙垢实验。结果显示：相同的药剂浓度，TH-658B的碳酸钙阻垢率均高于ATMP和HEDP。同时，TH-658B的碳酸钙和硫酸钙阻垢率均符合Q/SY 126-2007要求。梯度浓缩试验结果说明TH-658B可以使高硬、高碱水浓缩至钙硬、总碱之和大于1500mg/L而系统不结垢，远高于GB50050-2007的要求，这也为评价药剂的性能和适用范围提供了一个有效的新方法。此外，参照GB/T 18175-2000，在TH-658B的存在下，高硬、高碱配水（＞1500mg/L）中的碳钢、不锈钢和铜的腐蚀速率分别为0.036、0.0018、0.0012mm/a，均符合GB50050-2007的要求。此外还通过华北一电厂的现场应用，证明了TH-658B对高硬、高碱，特别是钙硬总碱之和达到1500 mg/L以上的高浓缩倍率循环水系统具有良好的缓蚀和阻垢效果。此外，TH-658B的磷含量仅为ATMP或HEDP的二分之一，符合水处理剂绿色、环保的发展方向。 关键词：高硬、高碱水；缓蚀阻垢剂TH-658B；性能；应用 中图分类号：TQ085 文献标识码：A 文章编号： Research on the performance and application of TH-658B scale and corrosion inhibitor for high hardness and high alkalinity water HE Mao-cai1, QI Xiao-jing1, GAO Can-zhu2 (1.Shandong Taihe Water Treatment Co.,Ltd., Zaozhuang 277100, China; 2. School of Environmental Science and Engineering, Shandong University, Jinan 250100, China) Abstract: Aiming at the scale and corrosion problem of high hardness and alkalinity water in North and Northwest of China, a new type scale and corrosion inhibitor TH-658B was developed. Performances of TH-658B were evaluated by the means of scale inhibition test, gradient concentration test and rotary coupon corrosion test, respectively. The results show that the calcium carbonate scale inhibition rate of TH-658B is higher than ATMP and HEDP under the same concentrations according to the standards of GB/T 16632-2008 and Q/SY 126-2007. The calcium carbonate and calcium sulfate scale inhibition rate of TH-658B are up to the standard requirements of Q/SY 126-2007. Gradient enrichment test results indicate that the summation of calcium hardness and total alkalinity could reach more than 1500mg/L as TH-658B existed in water, which is much higher than the standard requirements of GB50050-2007. In addition, it provided a new method to