甲烷自热重整制氢技术的研究进展.pdfVIP

Jan. 2006 现代化工 第 26 卷第 1 期 ·24 · Modern Chemical Industry 2006 年 1 月 甲烷自热重整制氢技术的研究进展 蔡秀兰 ,董新法 ,林维明 (华南理工大学化工与能源学院 ,广东 广州 510640) 摘要 :综述了甲烷自热重整反应制氢的研究进展情况 ,介绍了催化剂的活性组分、助催化剂、载体、钙钛矿型催化剂的研究 现状以及新的研究动向 ,并对积碳的形成及消除进行了简单介绍 ;另外 ,对金属膜分离法、水煤气变换法及一氧化碳选择性氧化 法等氢气纯化方法进行了讨论 ,指出钯膜反应器的甲烷转化率高 ,且能直接得到纯净的氢气。 关键词 : 甲烷; 自热重整;制氢 ;积碳 ;氢气纯化 ( ) 中图分类号:TQ22111 　 文献标识码 :A 　 文章编号 :0253 - 4320 2006 01 - 0024 - 04 Advances in autothermal reforming of methane to hydrogen CAI Xiulan , DONG Xinfa , LIN Weiming ( ) School of Chemical and Energy Engineering , South China University of Technology , Guangzhou 510640 , China Abstract : The advances in autothermal reforming of methane to hydrogen are reviewed. The status of research on active metal component ,additives and support ,and the formation and removing of coke are discussed. The methods of hydrogen purity by virtue of the metalmembrane separation ,watergas transformation and selective oxidation of CO were introduced. It was pointed out that the reversion rate of methane and the purity of hydrogen obtained were higher. Key words : methane ; autothermal reforming ; hydrogen preparation ; coke deposition ; hydrogen purity [1 ] 　　氢气是燃料电池的首选燃料 ,而天然气制氢则