沙柳液化制取生物油的研究.pdfVIP

沙柳液化制取生物油的研究 申请人： 边明世 陈雨 院系： 环境科学与工程系 指导教师： 张士成 摘要： 沙柳为原料，去离子水为介质，研究在温度240℃到340℃及2MPa N2 压力下直接液 化的情况。重点叙述了液化温度、固液比对液化产率的影响，在300℃固液比1:5 情况下产 油率达到了最大值40% 。并分析液化制取得的生物油的主要成分，通过GC-MS 对生物油的 测定，酚类与脂肪酸类是产物中最主要的两种物质，诸如2,6-二甲氧基苯酚，4-乙基-2- 甲氧 基苯酚， 2- 甲氧基酚，醋酸，丙酸，油酸等。生物油利用广泛，其中酚类化合物达到了生 [1] 物油产量的50%，酚类化合物可以作为生产绿色酚醛树脂的原料 。另外，沙柳液化后产生 的残渣具有良好的吸附性，可用作土壤改良。 关键词： 沙柳；液化；生物油；液化温度；固液比；生物油成分；应用 Abstract: Used Salix as raw material and deionized water as solvent. Direct liquefaction of Salix has been conducted at temperatures from 240℃to 340 ℃in the presence of 2 MPa N . Key described the 2 influence to the yield of bio-oil by the liquefaction temperature and solid-liquid ratio, The liquefaction operations at 300 ℃ and solid-liquid ratio of 1:5 that reached the maximum oil production rate of 40%; at the same time, we analyzed the main component of bio-oil obtained by liquefaction, As evidenced by GC–MS measurements, phenols and fatty acids are the two main substances, such as 2,6-dimethoxy-phenol, 4 - ethyl -2-methoxy-phenol, 2-methoxy-Phenol, acetic acid, propionic acid, oleic acid and so on. Bio-oil using a wide range, the concentration of phenolic compounds in the bio-oil was as high as about 50%, for the production of phenolic compounds that may be suitable for the production of green phenol–formaldehyde resins. [1] In addition, the residue which we have gotten after the liquefaction of Salix produced fine adsorption, which can be used to improve the function of soil. Keywords: Salix; Liquefaction; Bio-oil; Temperature of liquefaction; Solid-Liquid ratio; Bio-o