Tm3+Ho3+共掺硫卤玻璃的200μm荧光特性研究.pdfVIP

第 27 卷 第 7 期 无 机 材 料 学 报 Vol. 27 No. 7 2012 年 7 月 Journal of Inorganic Materials Jul., 2012 文章编号: 1000-324X201207-0711-05 DOI: 10.3724/SP.J.1077.2012.11483 3+ 3+ Tm /Ho 共掺硫卤玻璃的 2.00 μm 荧光特性研究 1,2 1,3 1,2 1,2 1,2 1,2 1,2 魏淑林 , 许银生 , 张培晴 , 陈飞飞 , 聂秋华 , 徐铁峰 , 戴世勋 宁波大学 1. 红外材料及器件实验室; 2. 信息科学与工程学院; 3. 材料科学与化学工程学院, 宁波 315211 3+ 3+ 摘 要: 通过真空 熔融淬 冷法制 备了不 同浓度 Tm /Ho 离子 共掺的 70GeS -20In S -10CsI 玻 璃样品, 分 析了样 品的 2 2 3 3+ 5 5 热 稳定性 及拉曼 光谱, 测试了 样品的 吸收光 谱以 及 808 nm 激光泵 浦下 Ho : I → I 辐 射跃迁 对应的 2.00 μm 荧光 7 8 3+ 3+ 光 谱特性. 结果 表明: Tm 离 子掺杂 浓度为 0.25mol% 时, 随着 Ho 离子 掺杂浓 度从 0.05mol%增加 到 0.125mol%, 3+ 3+ 3+ 3+ Tm 离子在 1.86 μm 的 发光强度 逐渐减 弱, Ho 离子 2.00 μm 荧 光明显 增强, 表明 Tm /Ho 离子之 间存 在有效 的能 量转移 关 键 词: 铥/ 钬共掺; 硫卤玻璃; 能量转移; 荧光特性 中图分类号: TQ171文献标识码: A 3+ 3+ 2.00 μm Emission Properties of Tm /Ho Co-doped Chalcohalide Glasses 1,2 1,3 1,2 1,2 1,2 WEI Shu-Lin , XU Yin-Sheng , ZHANG Pei-Qing , CHEN Fei-Fei , NIE Qiu-Hua ,1,2 1,2 XU Tie-Feng , DAI Shi-Xun 1. Laboratory of Infrared Material and Devices, Ningbo University, Ningbo 315211, China; 2. College of Information Science and Engineering, Ningbo University, Ningbo 315211,China; 3. The Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China Abstract: 2 μm laser has many potential applications on the medical surgery, laser radar, and pollution monitoring etc3+ 3+ Tm and Ho ions co-doped 70GeS -20In S -10CsI chalcohalide glasses were synthesized by vacuumed melting- 2 2 3 quenching technique. The DSC curves and Raman spectra showed that these glasses had good thermal stability and low phonon energy, respectively. The absorption and emission characteristics were evaluated with an emphasis on the 3+ 5 5 2.00 μm fluorescence from Ho : I → I transition. Under 808 nm excitation, the infrared emission bands extending 7 8 3+ 3+ from 1.80 μm to 2.10 μm can be seen on the emission spectra of the Tm and Ho ions co-doped glasses. This broad emission was consisted of two emission bands centered at 1.86 and