聚偏二氟乙烯高介电复合材料.pdfVIP

2013年摇 第37卷摇 摇 摇 摇 摇 摇 中国石油大学学报(自然科学版)摇 摇 摇 摇 摇 摇 摇 摇 Vol.37摇 No.5 摇 第5期摇 摇 摇 摇 摇 摇 摇 摇 Journal of China University of Petroleum摇 摇 摇 摇 摇 摇 摇 摇 Oct.2013 摇 摇 文章编号:1673鄄5005(2013)05鄄0196鄄05摇 摇 摇 doi:10.3969/ j.issn.1673鄄5005.2013.05.029 一纳米碳/ 聚偏二氟乙烯高介电复合材料 薛庆忠,褚良永,雷摇 拓 (中国石油大学理学院,山东青岛266580) 摘要:以多壁碳纳米管及多层石墨烯作为添加剂与聚偏二氟乙烯基体复合,制备介电性能优异的纳米碳/ 聚合物复 合材料。 通过SEM,TEM,AFM,XPS,FT鄄IR等手段对添加剂的结构、成分及其在聚合物基体中的分散性进行了表征。 对多壁碳纳米管进行羧基及酯基修饰后,提高其在聚合物基体中的分散性,复合材料的介电性能明显提高。 对多层 石墨烯进行强碱水热处理后,多层石墨烯表面羟基含量增加,多层石墨烯/ 聚偏二氟乙烯复合材料的导电阈值增加, 复合材料的介电性能大大增强,表现出比碳纳米管掺杂的复合材料更加优异的介电性能。 关键词:多壁碳纳米管;多层石墨烯;化学修饰;介电复合材料 中图分类号:TQ028摇 摇 摇 文献标志码:A Nano carbon/ poly (vinylidene fluoride) composites with high dielectric properties XUE Qing鄄zhong,CHU Liang鄄yong,LEI Tuo (College of Science in China University of Petroleum,Qingdao266580,China) Abstract: Polymer based composites with high dielectric properties were fabricated with multi鄄walled carbon nanotube (MWNTs) andfew layer graphene nanosheets (FLGs) acting as conductive fillers. Using methods such as SEM,TEM, AFM,XPS,FT鄄IR,the composition and structure of nano鄄sized carbon materials andtheir dispersion in the polymer matrix were measured andcharacterized. Aftercarboxylicandesterfunctionalization,thecompositesshow significantincreaseindi鄄 electric constantduetoimprovementofthedispersionof MWNTsinthepolymermatrix. Afterone鄄stepalkaline鄄mediatedhy鄄 drothermal treatment,hydroxyl content increases on the surface of the FLGs. The percolation threshold of FLGs/ polymer composites increases accordingly and the composites show better dielectric properties than nano鄄sized carbon materials. Key words:multi鄄walled carbon nanotube;few layer graphene nanosheets;chemical modification;dielectr