晶界偏聚理论中等效时间计算方法的若干问题探讨.docVIP

晶界偏聚理论中等效时间计算方法的若干问题探讨 张喜亮，刘涛1，刘争1，张维1，周昌玉2 河北工程大学 装备制造学院，河北 邯郸 056038） （2．南京工业大学 机械与动力工程学院，江苏 南京 200019） 摘要：对晶界偏聚理论中经常用到的等效时间计算方法进行深入讨论，偏聚中连续冷却阶段的等效是在恒温等效的基础上发展的，因此分别针对平衡晶界偏聚和非平衡晶界偏聚中的恒温阶段的等效时间方法进行系统的分析。研究结果表明随着两等效温度间差值的提高，利用等效时间公式计算得到的晶界偏聚浓度与实际真实的偏聚浓度误差不断增大，当两温度差值在60℃时，二者之间的误差达到103.9％。对于同一保温温度不同保温时间下，随着保温时间的增加，等效到各个温度下的等效晶界偏聚浓度与真实偏聚浓度误差也呈增大趋势。最后基于浓度相等理念推导并建立等效时间新的计算方法； 关键词：等效时间，平衡偏聚，非平衡偏聚，计算方法 中图分类号：TG14；TG113；TG156 文献标识码：A 文章编号： Insight into some aspects of calculation method for grain boundary segregation theory ZHANG Xi-liang1, LIU Tao1, CUI Guo-hua1, ZHOU Chang-yu2 Equipment manufacturing college, Hebei University of Engineering, Handan 056038, China) （2. School of Mechanical and Power Engineering, Nanjing University of Technology, Nanjing 210009,China） Abstract: The calculation method of equivalent time frequently used in grain boundary segregation theory was discussed in depth in this paper, and the method of thermostatic equivalent time, for equilibrium segregation and non-equilibrium segregation, was analyzed systematically because it was the foundation of equivalent calculation in continuously cooling process. The results reveal that the error, for grain boundary segregation concentration between calculation results according to equivalent time and true value, increases more apparently as the raise of the difference between the thermostatic temperature and equivalent temperature. The error reached 103.9％ as the temperature difference to be 60℃. Furthermore, it appears that the error enhanced gradually with increase of holding time at a certain thermostatic temperature. The new calculated method of equivalent time was proposed by virtue of the principle of equal segregation concentration. Key words: Equivalent time; Equilibrium segregation; Non-equilibrium segregation; Calculation method 引言 溶质晶界偏聚是引起晶界性能变化的一个重要原因，它可以显著降低晶界的断裂强度[1]。晶界偏聚方式可分为平衡偏聚和非平衡偏聚。1957年，英国著名学者McLean首先提出了平衡偏聚模型，至今仍然为学术界广泛引用。Aust等人于20世纪60年代最早提出关于热循环引起的非平衡晶界偏聚现象，80年代徐庭栋建立了非平衡