Fe3O4空心亚微米球的制备和吸波表征.pdfVIP

中国科技论文在线    Fe O 空心亚微米球的制备和吸波表征 3 4 包家兴，刘晓芳，于荣海 (北京航空航天大学材料科学与工程学院，北京 100191) 摘要：采用溶剂热法制得具有空心结构的单分散Fe O 亚微米球，该空心微球具有立方多晶 3 4 结构，且尺寸均匀，直径约800 nm。使用X 线衍射仪(XRD)、透射电子显微镜(TEM)、扫描 电子显微镜(SEM)和振动样品磁强计(VSM)对产物结构、形貌和磁性能进行表征，结果显示 单分散Fe3O4 亚微米球具有立方晶相，饱和磁化强度为90.8 emu/g ，使用微波矢量网络分析 仪测试样品在2~18 GHz 微波频率范围内的复介电常数和复磁导率，以探讨材料的微波损耗 机制。 关键词：无机非金属材料；Fe O /SiO 核壳结构；溶剂热法；吸波性能 3 4 2 中图分类号：TB383 文献标识码：A Synthesis and microwave absorption properties of hollow Fe O microspheres 3 4 Bao Jiaxing, Liu Xiaofang, Yu Ronghai (Department of Materials Science and Engineering, Beihang University, Beijing 100191, China) Abstract: Hollow Fe O microspheres have been synthesized by solvothermal method. The 3 4 microspheres are monodisperse with uniform size and polycrystal structure. The average diameter of the spheres is ~800 nm. The microstructure, morphology and magnetic properties of the core-shell structural microspheres were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and vibrating sample magnetometry (VSM). The results showed that the crystal forms of the hollow Fe3O4 microspheres are of cubic phase, and the saturation magnetization is 90.8 emu/g. In order to explore the absorbing properties of the particles, complex permittivity and complex permeability of the hollow Fe O microspheres were measured by