POSS改性聚氨酯UV树脂涂料的性能及其应用研究.pdfVIP

中国科技论文在线 POSS 改性聚氨酯 UV 树脂涂料的性能及其 应用研究 胡秀智，雷家珩** 5 （武汉理工大学理学院，武汉 430070） 摘要：紫外光固化聚氨酯丙烯酸酯涂料绿色无污染、生产效率高，代表未来涂料的发展方向， 但该涂料涂膜的耐热性较差、机械强度较低，限制了它的广泛应用。本文采用多面齐聚倍半 硅氧烷（POSS ）化学接枝改性PUA ，研究了POSS 改性 PUA （POSS-PUA ）对涂膜耐热性、 硬度、耐磨性的影响并优化了涂料配方。结果表明，POSS-PUA 对涂料的耐热性、硬度、耐 10 磨性有较好的提高。该涂料中当 POSS-PUA 低聚物占 27%左右，氰特六官能团 PUA 低聚物 占37%左右，光引发剂 184 占5%时性能最佳。固化膜硬度达到 99HD，耐磨度为0.0042g， 热分解温度比纯 PUA 的提高 50℃左右。 关键词：多面齐聚倍半硅氧烷；聚氨酯涂料；紫外光固化；应用研究 中图分类号：TK02；O621.2；TQ21 15 Properties and Application of POSS Monified Polyurethane UV Curable Coatings HU xiuzhi, LEI jiaheng (School of science,Wuhan University of technology, WuHan 430070) 20 Abstract: Polyurethane acrylate UV curable coating with pollution-free, high production efficiency, is the direction of development of coating in the future. But the curing film of the coating with poor heat resistance, low mechanical strength, which restrict its wide application. This paper used polyhedral oligomeric silsesquioxane (POSS) modified PUA and research on POSS modified PUA on the effects of the film heat resistance, hardness, wear resistance as well as 25 optimized coating formulation. The results show that the POSS-PUA improved the curing film of coating for heat resistance, hardness, wear resistance. In the coating formulation, when POSS-PUA oligomers accounted for about 27%, Cytec six functional group