白光LED用Sr3SiO5-Eu2+荧光粉的合成及发光特性--外文翻译中英对照.docVIP

附录 附录Ⅰ 英文文献原文 Synthesis and luminescence property of Sr3SiO5:Eu2+ phosphors for white LED CHENG Guang (程 光), LIU Quansheng (刘全生), CHENG Liqun (程利群), LU Liping (卢利平), SUN Haiying (孙海鹰), WU Yiqing (吴移清), BAI Zhaohui (柏朝晖), ZHANG Xiyan (张希艳), QIU Guanming (邱关明) (School of Materials Science and Engineering, Changchun University of Science and Technology, Changchun 130022, China) Received 29 September 2009; revised 23 March 2010 Abstract: Sr3SiO5:Eu2+ yellow phosphors for white LEDs were synthesized by high temperature solid state reaction method under a reductive atmosphere. The crystalline phases were examined with X-ray diffraction (XRD). Luminescence properties were studied, and effects of various fluxing agents BaCl2, MgF2, CaF2 and BaF2 on the emission spectra were also studied. The optimal Eu2+ concentration and flux were determined. Sr3SiO5: Eu2+ was obtained by firing the sample on optimal composition and fabrication process. The sample showed a broad excitation band from 300 to 500 nm and a broad band emission peaking at 561 nm. Keywords: phosphor; Sr3SiO5:Eu2+; fluxing agents; rare earths White LEDs have been widely applied in many fields for their merits such as energy saving, high efficiency, long life and reliability etc.. Up to now white LEDs fabricated by using GaN based blue LED as the excitation source and coating with Y3Al5O12:Ce3+ phosphors have attracted much attention due to the easy fabrication, low cost, and high brightness[1–4]. Since the LEDs with Y3Al5O12:Ce3+ phosphors generate cool white, phosphors emitting longer wavelength have been extensively studied. Silicate system is an excellent luminescent host with a stable crystal structure and high thermal stability. Many studies on phosphors with silicate as a host have been conducted[5–9]. The Eu2+-doped M2SiO4 (M=Ca, Sr, Ba) was investigated by Kim et al.[10] The emission peak of the phosphor is centered at 540 nm, showing shorter emission wavelength than Y3Al5O12:Ce3+. Warm white LED could not