[ BMIM] Cl 离子液体改性埃洛石为基质制备大孔RFCC 助剂.pdfVIP

第42卷 第2期 燃摇 料摇 化摇 学摇 学摇 报 Vol.42 No. 2 2014年2月 Journal of Fuel Chemistry and Technology Feb. 2014 文章编号:0253鄄2409(2014)02鄄0252鄄05 [BMIM]Cl离子液体改性埃洛石为基质制备大孔RFCC助剂 薛青松,王一萌 (华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室,上海摇 200062) 摘摇 要:以氯化1鄄丁基鄄3鄄甲基咪唑([BMIM]Cl)离子液体改性埃洛石为基质,以USY 为主剂制备了大孔渣油催化裂化 (RFCC)助剂,采用XRD、N 吸附、SEM等手段对制备的助剂进行了表征,以济南FCC原料油为原料,以济南平衡剂为主剂在 2 固定流化床(ACE鄄MODEL R+ MM)上测定了助剂的反应性能。 结果表明,在助剂的制备过程中,将离子液体先嫁接到具有 开放大孔管状结构的埃洛石上,有效阻止了分子筛碎屑、黏结剂等占据埃洛石的管道及其活性位,高温焙烧去除离子液体后, 保留了埃洛石的大孔结构,使制得的助剂具有高的催化裂化活性和良好的汽油选择性。 关键词:离子液体;催化裂化;埃洛石;大孔;助剂 中图分类号:TE624摇 摇 文献标识码:A Ionic liquid of [BMIM]Cl modified halloysite as matrix for preparation of macroporous RFCC additives XUE Qing鄄song,WANG Yi鄄meng (ShanghaiKey Laboratory of Green Chemistry and ChemicalProcess,Chemistry of Department, East ChinaNormal University,Shanghai摇 200062,China) Abstract:The residue fluid catalytic cracking (RFCC) additives containing macropores were prepared with 1鄄butyl鄄3鄄methylimidazolium chloride ([BMIM]Cl) of room temperature ionic liquid modified halloysite as matrix and the USY zeolite as base. X鄄ray powder diffraction and N adsorption鄄desorption were employed for 2 characterization of the crystallinity and macroporous structure of RFCC additives. The performance of RFCC additiveswere carried out over a confined fluidized bed fluidized bed (ACE鄄MODEL R+MM) with Jinan FCC feedstock and Jinan FCC balance catalyst. It was found that the ionic liquid strongly interacted with the surface hydroxyl of halloysite firstly during the preparation of RFCC additives,and then the strong interaction between ionic liquid and