松香甲基丙烯酸_羟乙酯均聚和共聚研究.pdfVIP

3 8 8 V o l. 38 N o. 8 20 10 8 JOURNA L O F NORTHEA ST FORE STRY UN IVER SITY A ug. 20 10 1) 余彩莉 宫青海 张发爱 ( 54 1004) 将松香与甲基丙烯酸羟乙酯( HEMA ) 合成的酯化物 通过自由基聚合的方法制备了均聚物和与 苯乙烯( S t) 的共聚物 红外光谱( IR ) 和核磁共振氢谱( 1HNM R ) 表征了产物的分子结构 分别 综合热分析仪 ( TGA ) 和差示扫描量热仪( D SC) 表征了产物的热稳定性和玻璃化转变温度结果表明: 松香 HEM A 酯的均聚反 应较难进行 过氧化苯甲酰是其均聚反应较好的引发剂; 松香 HEM A 酯与苯乙烯 ( St) 较易进行共聚反应 偶氮二 异 丁腈是共聚反应较好的引发剂; 共聚物的黏度和玻璃化转变温度随苯乙烯的 量的增加而增加 而均聚物热稳 定性好于共聚物 松香; 甲基丙烯酸羟乙酯; 酯化物; 均聚; 共聚 TQ 35 1. 471; TQ 20 3 H om opolym erization and Copolym eriza tion of th e E ster via Rosin and 2hy droxy ethyl M ethacry late /Y u Ca ili G ong Q ingh ai Zh ang F aa i( C ollege o f Chem istry and B iolog ica l Eng ineer ing G u ilin U niversity o f T echno logy Gu ilin 54 1004 P. R. Ch ina) / / Journal o f N o rtheast F orestry U niversity. - 20 10 38( 8) . - 12 3~ 125 A ros in este r w as prep ared from rosin and 2hydroxyethy l m eth acry late ( HEM A ) . R ad ica l hom opo lym eriza tion and copo lym er ization w ith sty rene in solution w ere investigated. T he struc tures of thu s prep ared hom opo lym er and copo lym er w ere ch aracter ized by Fourier tran sfe r in frared sp ectrom eter ( FTIR ) and nu c lear m agnetic hydrogen resonance 1 ( HNM R ) . T hermograv mi etr ic ana ly sis ( TGA ) and d ifferen tia l scanning calor mi etry ( DSC ) w ere used to determ ine their therm a l stab ility and g lass tran sition tem perature resp ectively. R esults show ed th at the hom opo lym er ization o f the ro sin es ter w as not so easy as copo lym er ization. T he benzoy l superox ide ( BPO ) and azob is isobu ty ronitrile ( A I