纤维素_离子液体溶液流变行为的研究.pdfVIP

第 30 卷 　第 12 期 纺 　织 　学 　报 Vol . 30 　No . 12 2009 年 12 月 Journal of Textile Research Dec . 　2009 ( ) 文章编号 2009 纤维素离子液体溶液流变行为的研究 闫红芹 (安徽工程科技学院 纺织面料重点实验室 , 安徽 芜湖 　241000) ( ) 摘 　要 　以离子液体 1丁基3甲基咪唑氯盐 [BMIM ] Cl 为溶剂 ,制备了不同质量分数的纤维素[BMIM ] Cl 溶液 , 利用 ARESRFS 旋转流变仪研究了溶液的稳态流变行为 ,讨论了剪切速率 、温度和纤维素含量等因素对溶液黏度和 非牛顿指数的影响 。结果表明:纤维素[BMIM ]Cl 溶液属于非牛顿假塑性流体 ,呈现切力变稀行为 ;溶液的表观黏 度随着剪切速率的升高而降低 ;随着温度的升高 ,溶液的结构黏度下降 ,非牛顿指数增加 ;纤维素含量的增加可使 溶液的结构黏度 、零切黏度和黏流活化能增大 ,使非牛顿指数降低 。 关键词 　离子液体 ; 纤维素溶液 ; 黏弹性 ; 流变 中图分类号 :TQ 352 　　　文献标志码 :A 　　　 Study on rheological property of celluloseionic liquids YAN Hongqin ( Key L aboratory of Textile Science Technology , A nhui University of Technology and Science , Wuhu , A nhui 　241000 , China) Abstract 　Cellulose[BMIM ] Cl solution with different cellulose concentrations was prepared by using the ionic liquid 1butyl3methylimidazolium chloridedispersion [BMIM ] Cl as the solvent . The steady rheological properties of the solution were investigated by means of ARESRFS rheometer . The influence of several factors including shear rate , temperature and cellulose concentration on viscosity and nonNewtonican index were also discussed. The results showed that cellulose[BMIM ] Cl solution was a typical p seudoplastic fluid exhibiting shear thinning phenomena . The apparent viscosity of solution decreased with increasing of the shear rate . With increasing of temperature , the structure viscosity index