1催化湿式氧化法处理糖蜜酒精废液的研究.pdf

60minGB9878 1996 4 3.4 CODCr 2 ABSTRACT Postgraduate: Xia Huili Supervisor: He Xingcun In this dissertation, the current treatment technologies of molasses alcohol wastewater were reviewed. The principle and properties of catalytic wet air oxidation (CWAO) were elaborated. The new methods of CWAO in the treatment to molasses alcohol wastewater were raised, and the foundational study about the application of CWAO was carried out. The main contents and results were presented as follows: 1. The characteristic and the pretreatment of molasses alcohol wastewater were studied. The results were as follows: (1) The wastewater was a high concentration and acid waste liquid. Some organic components of which polymerized above the temperature of 110and some discomposed and formed charcoal when the temperature reached about 167’above the temperature of 240 We adjusted the pH value to 8.0 or so with the cream of line, then flocculated and settled these suspended matter with the flocculating agent of PHP-2 or the composite flocculating agent of PHP-2 and PAC before injecting the wastewater. The procedure and the optimum condition were as follows: The suitable recruitment of PHP-2 was 0.9mg/L; and the stirring velocity was 200rpm. Under this condition the suspended matter precipitated completely in 6 minutes. If we chose the composite flocculating agent of PHP-2 and PAC, the suspended matter precipitated completely in 5-7 minutes when the recruitment was 30mg/L. 2. On the base of using the transitional elements and the rare earth elements, we prepared various types composite catalysts, and evaluated them in a intermittent