1催化亚临界水氧化法处理糖蜜酒精废液的研究.pdf

Study on Catalytic Subcritical Water Oxidation of Molasses Alcohol Wastewater Master Candidate: Yu Saibo Supervisor: Associate Prof. Chen Menglin and Prof. He Xingcun Abstract In this dissertation, the current treatment technologies of molasses alcohol wastewater are reviewed. The characteristics of the Catalytic Wet Air Oxidation (CWAO), the Supercritical Water Oxidation (SCWO) and the Catalytic Supercritical Water Oxidation (CSCWO), with their study status in the treatment of organic wastewater are elaborated. And then, according to the characteristic of molasses alcohol wastewater, a new technique for treating the molasses alcohol wastewater, Catalytic Subcritical Water Oxidation (CSWO), is put forward and the basic study on the application of CSWO is carried through. The content and conclusion of the research are listed below. 1. The characteristic of molasses alcohol wastewater is analyzed. The results are as follows: molasses alcohol wastewater is a kind of high concentration acid organic wastewater, and there is a great quantity of heat to be produced, which can maintain the heat required by the reaction, when it is in the process of CSWO. At the temperature of 110 , it was found that some organics polymerized and at the temperature of 167 , some organics were decomposed to produce carbon. When there is oxygen, it won’t polymerize and precipitate carbon over the temperature of 240. The acidity of the wastewater should be adjusted and the suspended solids should be eliminated before the CSWO in order to avoid the erosion of the reactor by acid substances. 2. The neutralization-sedimentation treatment of the molasses alcohol wastewater is researched. Firstly, the waste