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60 5 Vol60 No5
2009 5 CIESC Journal May 2009
刘 喆, 章 莉, 金 涌, 程 易
( , , 100084)
: , , , ,
,
O/ W ,
;
, 5 J g- 1
: ; ; ; ;
: T Q 316 : A : 0438- 115 (2009) 05- 1292- 08
Preparation of phase change material microcapsules by
microreactor and solvent evaporation approach
LIU Zhe, ZHANG Li, IN Yong, CHENGYi
(K ey L aboratory of Green Chemical Reaction Eng ineer ing and Technology of Beij ing ,
D ep artment of Chemical E ng ineer ing, Ts inghua Uni ers ity , Beij ing 100084, China)
Abstract: T he phase change material ( PCM) microcapsules w ith polysulfone shell and nhexadecane core
w ere prepared in this w orkIn order to control the properties of PCM microcapsules, such as the size and
size distribution, the preparation process was decoupled into tw o separate stages: firstly, the
monodispersed O/ W droplets w ere generated by a microreactor; secondly, the droplets w ere solidified in a
bath by solvent evaporation approachT he effects of continuous phase flow rate, disperse phase flow rate,
and the microchannel size on the droplet formation process in the microreactor w ere studied
comprehensivelyT he PCM microcapsules w ere characterized by SEM and DSCThe results show ed that
- 1
the size of microcapsules w as uniform, and the latent heat w as greater than 5 J g .
Key words: phase change material; microcapsule; microreactor; solvent evaporation; process decoupling
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