磺酸基功能化MCM_41有机_无机杂化材料的合成与表征_英文_.pdfVIP

第 26 卷 第 5 期 催 　化 　学 　报 2005 年 5 月 Vol . 26 No . 5 Chi nese J ou rnal of Cat alys is May 2005 Article ID :(2005) Communication : 357～359 Synthesis and Characterization of MCM41- SO H 3 OrganicInorganic Hybrids GAO Guohua , ZHOU Wenj uan , HE Min gyuan ( S hang hai Key L aboratory of Green Chem is t ry an d Chem ical Process , Dep art ment of Chem is t ry , Eas t China N orm al University , S hang hai 2 00062 , China) Key words : MCM4 1 , mesoporous organicinorganic hybrid , acetalization CLC number : O643 　　　Document code : A 　　Mesoporous MCM4 1 materials , which were adecylt rimet hylammonium bromide ( C TAB ) . In a fir st synt hesized by researcher s at Mobil Corporation t ypical p rep aration , a mixt ure cont aining C TAB in 1992 , have a uniform hexagonal array of mesopores (2 73 g) , N aOH ( 124 g) and H O ( 140 g) was 2 wit h high surface area , adj ust able pore size and high stirred for 1 h . Organo silane a ( 157 g) and TEO S t hermal st ability . However , p ure silica MCM4 1 has ( 12 5 g) were added dropwise